Ernesto Costa-Villén, Mercè Font-Bardia, Júlia Mayans and Albert Escuer*,
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引用次数: 0
Abstract
A family of discrete dinuclear complexes [MIILnIII] (M = Cu, Ni and Ln = Ce, Gd, Tb, Dy, Er, Yb) has been synthesized from the use of the compartmental Schiff base ligand H4L (3,3′-((1E,1′E)-(ethane-1,2-diylbis(azaneylylidene)) bis(methaneylylidene))bis(benzene-1,2-diol)), obtained from the condensation of ethylenediamine and 2,3-dihydroxybenzaldehyde. All of the complexes have been structurally and magnetically characterized. The dynamic magnetic measurements show that the [CuIILnIII] and [NiIILnIII] derivatives exhibit ac response as a function of the d-cation. Noteworthily, the isotropic GdIII complexes exhibit a slow relaxation of magnetization.
A family of discrete dinuclear complexes [MIILnIII] (M = Cu, Ni, and Ln = Ce, Gd, Tb, Dy, Er, Yb) has been synthesized from the use of the compartmental Schiff base ligand H4L (3,3′-((1E,1′E)-(ethane-1,2-diylbis(azaneylylidene)) bis(methaneylylidene))bis(benzene-1,2-diol)), obtained from the condensation of ethylenediamine and 2,3-dihydroxybenzaldehyde.
期刊介绍:
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.