Tank-Mix Adjuvants Enhance Pesticide Efficacy by Improving Physicochemical Properties and Spraying Characteristics for Application to Cotton with Unmanned Aerial Vehicles

IF 3.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ACS Omega Pub Date : 2024-07-02 DOI:10.1021/acsomega.4c04301
Hongyan Hu, Yajie Ma, Xianpeng Song, Dan Wang, Xiangliang Ren, Changcai Wu, Chunhong Liu, Xiaoyan Ma, Yongpan Shan*, Yanhua Meng* and Yan Ma*, 
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Abstract

Tank-mix adjuvants have been used to reduce spray drift and facilitate the efficacy of pesticides applied with unmanned aerial vehicles (UAVs). However, the effects of specific adjuvants on pesticide characteristics and the mechanism of action remain unclear. Herein, we analyzed the effects of three different types of tank-mix adjuvants (plant oil; mineral oil; and mixture of alcohol and ester) on the surface tension (ST), contact angle, wetting, permeation, evaporation, spray performance, and aphid-control effects of two types of pesticides. The mineral oil adjuvant Weichi (WCH) was highly effective in reducing the pesticide solution ST, improving the wetting and penetration ability, increasing droplet size, and promoting droplet deposition. The mixed alcohol and ester adjuvant Quanrun (QR) showed excellent wetting and antievaporation properties and promoted droplet deposition. A plant oil adjuvant (Beidatong) moderately improved wetting and penetration ability and reduced droplet drift. Field tests showed that the control efficiencies (CEs) of two pesticides were increased after the addition of adjuvants, even with 20% reductions in pesticide application. When the UAV was operated at 1.5 m, the CEs of two pesticides were increased from 65.39 and 66.63% to 73.11–76.52% and 77.91–88.31%, respectively. When operated at 2.5 m, the CEs were increased from 51.24 and 68.60% to 65.06–75.70% and 77.57–92.59%, respectively. Especially, the CEs of pesticides with WCH and QR increased obviously. Importantly, neither WCH nor QR inhibited hatching of the critical insect natural enemy ladybird beetle at concentrations used in the field. This study provides a framework for assessment of tank-mix adjuvants in aerial sprays and directly demonstrates the value of specific adjuvants in improving pesticide bioavailability and minimizing associated environmental pollution.

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罐装混合佐剂通过改善理化性质和喷洒特性来提高杀虫剂的药效,以便用无人驾驶飞行器喷洒棉花
罐装混合佐剂已被用于减少喷洒漂移,提高无人驾驶飞行器(UAV)施用农药的功效。然而,特定佐剂对农药特性和作用机制的影响仍不清楚。在此,我们分析了三种不同类型的罐混佐剂(植物油、矿物油、醇和酯的混合物)对两种农药的表面张力(ST)、接触角、润湿性、渗透性、蒸发性、喷雾性能和蚜虫防治效果的影响。矿物油佐剂 Weichi(WCH)在降低农药溶液 ST、提高润湿和渗透能力、增大雾滴尺寸和促进雾滴沉积方面效果显著。混合醇和酯佐剂 Quanrun(QR)具有出色的润湿和防蒸发性能,并能促进液滴沉积。植物油佐剂(Beidatong)适度提高了润湿和渗透能力,减少了液滴漂移。现场测试表明,添加佐剂后,即使农药施用量减少 20%,两种农药的控制效率(CE)也有所提高。当无人机在 1.5 米处运行时,两种农药的控制效率分别从 65.39% 和 66.63% 提高到 73.11%-76.52% 和 77.91%-88.31%。在 2.5 米处操作时,CE 分别从 51.24 和 68.60% 增加到 65.06-75.70% 和 77.57-92.59%。特别是使用 WCH 和 QR 的农药的 CE 值明显增加。重要的是,在田间使用的浓度下,WCH 和 QR 都不能抑制重要昆虫天敌瓢虫的孵化。这项研究为空中喷雾中的罐混佐剂评估提供了一个框架,并直接证明了特定佐剂在提高农药生物利用率和减少相关环境污染方面的价值。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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