Kinetically Controlled Acid–Base Interaction of Tetra-4-chloro-tetra-5(5-methyl-2-isopropylphenoxy)phthalocyanine with Nitrogen-Containing Organic Bases
O. A. Petrov, E. V. Shagalov, A. N. Kiselev, V. E. Maizlish, I. G. Abramov
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引用次数: 0
Abstract
The interaction of the first synthesized tetra-4-chloro-tetra-5(5-methyl-2-isopropylphenoxy)phthalocyanine with pyridine, 2-methylpyridine, morpholine, piperidine, n-butylamine, tert-butylamine, diethylamine, and triethylamine in benzene was studied. The acid–base reaction is one of the rarely observed slow processes that forms kinetically stable proton transfer complexes. The structure of the complexes is described. The reactivity of tetra-4-chloro-tetra-5(5-methyl-2-isopropylphenoxy)phthalocyanine changes depending on the proton-acceptor ability and spatial structure of the nitrogen-containing base.
期刊介绍：
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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