Arne Nisters, Torsten Gutmann, Sun-Myung Kim, Jan Philipp Hofmann and Marcus Rose
{"title":"A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2†","authors":"Arne Nisters, Torsten Gutmann, Sun-Myung Kim, Jan Philipp Hofmann and Marcus Rose","doi":"10.1039/D4SU00164H","DOIUrl":null,"url":null,"abstract":"<p >Porous organic polymers enable a novel approach to incorporate xantphos into a solid macroligand. Immobilizing a ruthenium complex on the xantphos framework results in an excellent catalyst for the hydrogenation of CO<small><sub>2</sub></small> to formic acid. Recycling experiments indicate a minor partial degradation of the heterogenous catalyst after a certain induction period, which is referred to its structural changes.</p>","PeriodicalId":74745,"journal":{"name":"RSC sustainability","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/su/d4su00164h?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"RSC sustainability","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/su/d4su00164h","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Porous organic polymers enable a novel approach to incorporate xantphos into a solid macroligand. Immobilizing a ruthenium complex on the xantphos framework results in an excellent catalyst for the hydrogenation of CO2 to formic acid. Recycling experiments indicate a minor partial degradation of the heterogenous catalyst after a certain induction period, which is referred to its structural changes.