{"title":"Kinetics of the Diels–Alder Reaction of Thiofluorenone with 9,10-Dimethylanthracene","authors":"D. A. Kornilov, A. G. Mustafin","doi":"10.1134/S1070428024040055","DOIUrl":null,"url":null,"abstract":"<p>Rate constants of the Diels–Alder reaction of thiofluorenone and 9,10-dimethylanthracene in toluene have been determined in the temperature range of 15 to 35°C, and the enthalpy and entropy of activation have been calculated. The structure of the resulting adduct was determined by NMR spectroscopy, mass spectrometry, and elemental analysis.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070428024040055","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
Rate constants of the Diels–Alder reaction of thiofluorenone and 9,10-dimethylanthracene in toluene have been determined in the temperature range of 15 to 35°C, and the enthalpy and entropy of activation have been calculated. The structure of the resulting adduct was determined by NMR spectroscopy, mass spectrometry, and elemental analysis.
期刊介绍：
Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.
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