A Comprehensive Review on Lignin Based Electrospun Nanomaterials as Suitable Adsorbents for Remediation of Detrimental Water and Air Pollutants

IF 3.8 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Water, Air, & Soil Pollution Pub Date : 2024-07-03 DOI:10.1007/s11270-024-07280-5
Sayantan Ghosh, Krishna Pramanik
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Abstract

Lignin is an amorphous natural polymer with multifunctional phenolic network accounting for approximately 15–30% of lignocellulosic biomass. Different functional groups like carboxyl, hydroxyl, phenolic and methoxy in lignin molecule may act as suitable interaction sites for the removal of pollutants. Lignin, as an abundant and renewable bioresource, can be used to create nanofibrous membranes via electrospinning technique. Such nanofibrous membranes with elevated specific surface area, uniform fiber diameter, and high porosity may serve as highly efficient adsorbents for the entrapment of detrimental pollutants like dyes, heavy metals, particulates, etc. Hence, numerous research has been carried out to develop lignin based electrospun membranes in recent years. For example, a low-cost electrospun nano-fibrous membrane (ENM) comprising of alkali lignin/polyvinyl alcohol (PVA) was developed for effective removal of Safranine T dye. Similarly, palm fronds and banana bunch waste biomass derived lignin was successfully employed as an electrospun material for the removal of methylene blue dye. An alkali lignin/PVA ENM was developed for the adsorption of fluoxetine contaminant from its solution. This review paper provides the up-to-date information on the development and usage of eco-friendly, sustainable and cost-effective electrospun lignin nano-adsorbents for the removal of various environmental contaminants.

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关于木质素电纺纳米材料作为修复有害水和空气污染物的合适吸附剂的综述
木质素是一种具有多功能酚网络的无定形天然聚合物,约占木质纤维素生物质的 15-30%。木质素分子中的羧基、羟基、酚基和甲氧基等不同官能团可作为去除污染物的合适相互作用位点。木质素作为一种丰富的可再生生物资源,可通过电纺丝技术制成纳米纤维膜。这种纳米纤维膜具有较高的比表面积、均匀的纤维直径和较高的孔隙率,可作为高效吸附剂吸附染料、重金属、微粒等有害污染物。因此,近年来人们开展了大量研究来开发基于木质素的电纺丝膜。例如,开发了一种由碱木质素/聚乙烯醇(PVA)组成的低成本电纺纳米纤维膜(ENM),可有效去除 Safranine T 染料。同样,从棕榈叶和香蕉束废弃生物质中提取的木质素也被成功用作去除亚甲基蓝染料的电纺材料。还开发了一种碱木素/PVA ENM,用于吸附溶液中的氟西汀污染物。本综述论文提供了有关开发和使用生态友好、可持续和经济高效的电纺木质素纳米吸附剂去除各种环境污染物的最新信息。
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来源期刊
Water, Air, & Soil Pollution
Water, Air, & Soil Pollution 环境科学-环境科学
CiteScore
4.50
自引率
6.90%
发文量
448
审稿时长
2.6 months
期刊介绍: Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments. Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation. Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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