{"title":"Removal of Ammonium and Manganese from Water by MnOx Media: Establishment of Film Growth Kinetic Model and Chemical Peeling Film Mechanism","authors":"Zhekai Zhang, Yingming Guo, Manman Cao, Kai Li","doi":"10.1007/s11270-024-07295-y","DOIUrl":null,"url":null,"abstract":"<p>Manganese oxide (MnO<sub>x</sub>) on the surface of the filter material can be used to effectively remove ammonium (NH<sub>4</sub><sup>+</sup>) and manganese ions (Mn<sup>2+</sup>) from water, but overgrow oxide film gradually shortens backwashing interval after several years of long-term filtration system operation. Different influent pollutant loading result in different durations for chemical peeling film. A growth kinetics model for MnO<sub>x</sub> was established by adjusting the different initial concentrations of Mn<sup>2+</sup> in the influent, which provided a theoretical basis for determining a specific time point for film peeling and recovered the shortened backwashing intervals in the filter columns. The variation in film thickness demonstrated a linear dependence on time, confirming the high accuracy of the kinetics model for film growth. The pseudo-first-order kinetic model better fits among adsorption and oxidation kinetic models of Mn<sup>2+</sup>. Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) was identified as an effective agent in the chemical peeling film process. Hydroxyl radicals, generated by H<sub>2</sub>O<sub>2</sub>, destroy coordination bonds, producing extremely low solubility (≡MnO<sub>2</sub>), which was then removed during the backwashing process.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\n","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water, Air, & Soil Pollution","FirstCategoryId":"6","ListUrlMain":"https://doi.org/10.1007/s11270-024-07295-y","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
Manganese oxide (MnOx) on the surface of the filter material can be used to effectively remove ammonium (NH4+) and manganese ions (Mn2+) from water, but overgrow oxide film gradually shortens backwashing interval after several years of long-term filtration system operation. Different influent pollutant loading result in different durations for chemical peeling film. A growth kinetics model for MnOx was established by adjusting the different initial concentrations of Mn2+ in the influent, which provided a theoretical basis for determining a specific time point for film peeling and recovered the shortened backwashing intervals in the filter columns. The variation in film thickness demonstrated a linear dependence on time, confirming the high accuracy of the kinetics model for film growth. The pseudo-first-order kinetic model better fits among adsorption and oxidation kinetic models of Mn2+. Hydrogen peroxide (H2O2) was identified as an effective agent in the chemical peeling film process. Hydroxyl radicals, generated by H2O2, destroy coordination bonds, producing extremely low solubility (≡MnO2), which was then removed during the backwashing process.
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Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments.
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Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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