{"title":"1,2-Bis(phenylsulfonyl)ethylene (BPSE): A Potent Radical C2 Synthon Available in the Radical and Electron-Transfer-Based Organic Synthesis","authors":"Shuhei Sumino, Ilhyong Ryu, Frédéric Robert, Yannick Landais","doi":"10.1055/s-0043-1775374","DOIUrl":null,"url":null,"abstract":"<p>In this Short Review, we discuss radical reactions using 1,2-bis(phenylsulfonyl)ethylene (BPSE), which has drawn significant attention as a versatile building block for (phenylsulfonyl)ethenylation. Regardless of its <i>E</i> or <i>Z</i> form, BPSE exhibits reliable reactivity towards the attack of alkyl and aryl radicals in order to function as a reliable radical C2 synthon.</p> <p>1 Introduction</p> <p>2 Use in Radical Chain Reactions</p> <p>3 Use in Reactions Utilizing an Electron-Transfer Process</p> <p>4 Use in Radical-Based C–H Alkenylation</p> <p>5 Conclusion</p> ","PeriodicalId":501298,"journal":{"name":"Synthesis","volume":"60 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/s-0043-1775374","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
In this Short Review, we discuss radical reactions using 1,2-bis(phenylsulfonyl)ethylene (BPSE), which has drawn significant attention as a versatile building block for (phenylsulfonyl)ethenylation. Regardless of its E or Z form, BPSE exhibits reliable reactivity towards the attack of alkyl and aryl radicals in order to function as a reliable radical C2 synthon.
1 Introduction
2 Use in Radical Chain Reactions
3 Use in Reactions Utilizing an Electron-Transfer Process
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