Development of Effective Depressor Additives to Diesel Fuel, Based on Copolymers of Stearyl Methacrylate with Monomers of Various Structures

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED Russian Journal of Applied Chemistry Pub Date : 2024-06-10 DOI:10.1134/S1070427223100026
E. V. Kolyakina, M. V. Pavlovskaya, Yu. S. Pronina, S. D. Zaitsev, D. F. Grishin
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Abstract

Depressor additives based on stearyl methacrylate homopolymer and its copolymers with various monomers (butyl methacrylate, methacrylic acid esters of С10–С14 fraction, maleic anhydride) were synthesized in the presence of reversible addition–fragmentation chain-transfer agents allowing control of the molecular-weight characteristics of the polymers. The low-temperature properties of the diesel fuel containing additives based on the above polymers were evaluated. The copolymers exhibit the better depressor effect compared to the stearyl methacrylate homopolymer. Modification of the stearyl methacrylate–maleic anhydride copolymer with 1-octanol was performed. The modified additive well competes in performance with the modern commercial depressor-dispersing additives and can decrease the congealing point of hydrotreated diesel fuels by 20°С.

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以甲基丙烯酸硬脂酯与不同结构单体的共聚物为基础,开发有效的柴油减压添加剂
摘要 在可逆加成-断裂链转移剂的作用下,合成了基于甲基丙烯酸硬脂酯均聚物及其与各种单体(甲基丙烯酸丁酯、С10-С14馏分的甲基丙烯酸酯、马来酸酐)的共聚物的减压添加剂,从而控制了聚合物的分子量特性。对含有基于上述聚合物的添加剂的柴油的低温特性进行了评估。与甲基丙烯酸硬脂酯均聚物相比,共聚物具有更好的抑制效果。研究人员用 1-辛醇对甲基丙烯酸硬脂酯-马来酸酐共聚物进行了改性。改性后的添加剂在性能上可与现代商用减压分散添加剂相媲美,并可将加氢处理柴油的凝固点降低 20°С。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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