Lichen Exometabolites as Possible Precursors of Secondary Organic Aerosols

IF 0.9 Q4 OPTICS Atmospheric and Oceanic Optics Pub Date : 2024-07-03 DOI:10.1134/S1024856024700210
M. P. Tentyukov, B. D. Belan, D. V. Simonenkov, S. A. Patov, V. I. Mikhailov, G. V. Simonova, S. N. Plyusnin, Yu. A. Bobrov
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Abstract

Lichens are not only a bioindicator of air pollution; they also affect the chemical composition of air. The qualitative composition of exometabolites in thalli of epiphytic lichens is studied using high-performance liquid chromatography. The comparative analysis of the fractional composition of deposited aerosol matter in water washouts of lichens shows it to be characterized by a bimodal particle distribution. It is postulated that the appearance of the fine fraction is associated with the generation of secondary organic aerosols on the surface of epiphytic lichens. Their precursors are the products of photoactivated reactions between deposited aerosol matter and highly volatile organic compounds which arrive on the lichen surface as a result of efflorescence. The mechanism of entry of secondary organic aerosols into the surface air layer under the radiometric photophoresis effect is discussed.

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作为二次有机气溶胶可能前体的地衣外代谢物
摘要地衣不仅是空气污染的生物指标,还影响着空气的化学成分。本文采用高效液相色谱法研究了附生地衣鳞茎中外代谢物的定性组成。通过比较分析地衣水冲洗过程中沉积气溶胶物质的部分组成,发现其具有双峰颗粒分布的特点。据推测,细小颗粒的出现与附生地衣表面生成二次有机气溶胶有关。它们的前体是沉积气溶胶物质和高挥发性有机化合物之间的光活化反应产物,这些有机化合物是地衣表面风化的结果。本文讨论了二次有机气溶胶在辐射光吸收效应下进入地表空气层的机制。
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来源期刊
CiteScore
2.40
自引率
42.90%
发文量
84
期刊介绍: Atmospheric and Oceanic Optics  is an international peer reviewed journal that presents experimental and theoretical articles relevant to a wide range of problems of atmospheric and oceanic optics, ecology, and climate. The journal coverage includes: scattering and transfer of optical waves, spectroscopy of atmospheric gases, turbulent and nonlinear optical phenomena, adaptive optics, remote (ground-based, airborne, and spaceborne) sensing of the atmosphere and the surface, methods for solving of inverse problems, new equipment for optical investigations, development of computer programs and databases for optical studies. Thematic issues are devoted to the studies of atmospheric ozone, adaptive, nonlinear, and coherent optics, regional climate and environmental monitoring, and other subjects.
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