Crystals of Salts of Nickel and Cobalt Transition Elements for Optical Filters

IF 0.6 4区 材料科学 Q4 CRYSTALLOGRAPHY Crystallography Reports Pub Date : 2024-06-06 DOI:10.1134/s1063774524600066
V. L. Manomenova, E. B. Rudneva, N. A. Vasilyeva, N. I. Sorokina, V. A. Komornikov, D. S. Matveeva, M. S. Lyasnikova, V. V. Grebenev, S. I. Kovalev, A. E. Voloshin
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Abstract

The results of the studies performed at the Shubnikov Institute of Crystallography and devoted to the development of UV optical filters based on complex nickel and cobalt compounds are reviewed. The structural dependence of the optical properties of these crystals and their thermal stability is discussed. The fundamental features of mixed crystals grown from solution and developed approaches to the design of optical filters based on structurally perfect mixed K2(Co,Ni)(SO4)2⋅6H2O crystals are described. The possibility of designing UV-А optical filters by partial substitution of the ligand environment of transition metal ions is demonstrated.

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用于光学滤波器的镍和钴过渡元素盐晶体
摘要 回顾了舒布尼科夫晶体学研究所为开发基于复杂镍和钴化合物的紫外线光学过滤器而进行的研究成果。文章讨论了这些晶体光学特性的结构依赖性及其热稳定性。介绍了从溶液中生长的混合晶体的基本特征,以及基于结构完美的 K2(Co,Ni)(SO4)2⋅6H2O 混合晶体设计光学滤光片的方法。证明了通过部分替换过渡金属离子的配体环境来设计 UV-А 光学过滤器的可能性。
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来源期刊
Crystallography Reports
Crystallography Reports 化学-晶体学
CiteScore
1.10
自引率
28.60%
发文量
96
审稿时长
4-8 weeks
期刊介绍: Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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