Solid Solutions of Pyridinium Halobismuthates

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI:10.1134/s003602362360288x
P. A. Buikin, A. S. Zhavoronkov, A. B. Ilyukhin, V. Yu. Kotov
{"title":"Solid Solutions of Pyridinium Halobismuthates","authors":"P. A. Buikin, A. S. Zhavoronkov, A. B. Ilyukhin, V. Yu. Kotov","doi":"10.1134/s003602362360288x","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Solid solutions of pyridinium bromo-iodobismutates have been isolated from aqueous solutions and structurally characterized. The composition of the resulting solid solutions [HPy]BiX<sub>4</sub> and [HPy]<sub>3</sub>Bi<sub>2</sub>X<sub>9</sub> (X = Br, I) depends on the ratios of organic cation/bismuth and bromine/iodine in the initial solution. The existence of five polymorphic modifications in the system for compositions [HPy]BiX<sub>4</sub> has been shown. Two different polymorphs have been found for iodobismuthate [HPy]BiI<sub>4</sub>.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"24 1","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s003602362360288x","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Solid solutions of pyridinium bromo-iodobismutates have been isolated from aqueous solutions and structurally characterized. The composition of the resulting solid solutions [HPy]BiX4 and [HPy]3Bi2X9 (X = Br, I) depends on the ratios of organic cation/bismuth and bromine/iodine in the initial solution. The existence of five polymorphic modifications in the system for compositions [HPy]BiX4 has been shown. Two different polymorphs have been found for iodobismuthate [HPy]BiI4.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
吡啶鎓卤铋盐固溶体
摘要 从水溶液中分离出了溴碘铋酸吡啶鎓固溶体,并对其结构进行了表征。所得固溶体 [HPy]BiX4 和 [HPy]3Bi2X9 (X = Br, I) 的组成取决于初始溶液中有机阳离子/铋和溴/碘的比例。研究表明,[HPy]BiX4 成分在该体系中存在五种多晶形态。碘铋酸盐 [HPy]BiI4 发现了两种不同的多晶型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
期刊最新文献
Luminescence Features of Multicomponent Cubic Fluoride Pyrochlores Doped with Europium Ions Synthesis and Thermodynamic Properties of Thulium Titanate Carboxonium Derivatives of closo-Decaborate Anion [2,6-B10H8O2CC6H4R]– Based on Aromatic Carboxylic Acids: Synthesis and Physicochemical Properties Isotope Effect in IR Spectra of Highly Enriched Amorphous Silicon Dioxide ASiO2 (A = 28, 29, 30) Synthesis, Crystal Structure, and Thermodynamic Properties of Ca3Y2Ge3O12
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1