Gauthier Deblonde , Ian Colliard , Y. Ozawa (Editor)
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引用次数: 0
Abstract
The cystallization and capture of hexachlorothallium within the phosphotunsgate and caesium chloride matrix is described.
Crystal formation of caesium thallium chloride phosphotungstates, Cs9(TlCl6)(PW12O40)2·9CsCl showcases the ability to capture and crystallize octahedral complexes via the use of polyoxometalates (POMs). The large number of caesium chlorides allows for the POM [α-PW12O40]3− to arrange itself in a cubic close-packing lattice extended framework, in which the voids created enable the capture of the [TlCl6]3− complex.
期刊介绍：
Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.
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