Effect of Bismuth Oxide on the Structure, Electrical Resistance, and Magnetization of Lithium Zinc Ferrite

IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Physics of Metals and Metallography Pub Date : 2024-07-08 DOI:10.1134/s0031918x2460009x
S. A. Nikolaeva, Yu. S. Elkina, E. N. Lysenko, E. V. Nikolaev, V. A. Vlasov
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Abstract

The structural, electrical, and magnetic properties of lithium zinc ferrite prepared by ceramic technology have been studied. The composition of lithium zinc ferrite is Li0.4Fe2.4Zn0.2O4 with 1 and 2 wt % bismuth oxide. The addition of Bi2O3 prior to sintering of the samples has been shown to affect the structural, electrical, and magnetic properties of the ferrite. A significant increase in density from 4.47 to 4.65 g/cm3 and a decrease in porosity from 4.8 to 2.3% have been observed when the concentration of bismuth oxide has been increased to 2 wt %. The Bi2O3-containing samples have higher specific electrical resistivity compared to that of the additive-free lithium zinc ferrite. The introduction of bismuth oxide has reduced the specific saturation magnetization from 70.55 to 54.76 G cm3/g. The Curie temperature has not changed significantly. An optimal combination of macroscopic properties of ferrite has been found at 1 wt % Bi2O3 concentration.

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氧化铋对锂锌铁氧体结构、电阻和磁化的影响
摘要 研究了利用陶瓷技术制备的锂锌铁氧体的结构、电学和磁学特性。锂锌铁氧体的成分是 Li0.4Fe2.4Zn0.2O4 与 1 和 2 wt % 的氧化铋。研究表明,在样品烧结前加入 Bi2O3 会影响铁氧体的结构、电学和磁学特性。当氧化铋的浓度增加到 2 wt % 时,密度从 4.47 g/cm3 显著增加到 4.65 g/cm3,孔隙率从 4.8% 降低到 2.3%。与不含添加剂的锂锌铁氧体相比,含 Bi2O3 的样品具有更高的比电阻率。引入氧化铋后,比饱和磁化率从 70.55 G cm3/g 降至 54.76 G cm3/g。居里温度没有明显变化。在 Bi2O3 浓度为 1 wt % 时,找到了铁氧体宏观特性的最佳组合。
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来源期刊
Physics of Metals and Metallography
Physics of Metals and Metallography 工程技术-冶金工程
CiteScore
2.00
自引率
25.00%
发文量
108
审稿时长
3 months
期刊介绍: The Physics of Metals and Metallography (Fizika metallov i metallovedenie) was founded in 1955 by the USSR Academy of Sciences. Its scientific profile involves the theory of metals and metal alloys, their electrical and magnetic properties, as well as their structure, phase transformations, and principal mechanical properties. The journal also publishes scientific reviews and papers written by experts involved in fundamental, application, and technological studies. The annual volume of publications amounts to some 250 papers submitted from 100 leading national scientific institutions.
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