Adsorption and transport of acid dye through polymer inclusion membrane with Aliquat 336 and TBP

IF 3.8 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Water, Air, & Soil Pollution Pub Date : 2024-07-08 DOI:10.1007/s11270-024-07318-8
Aynur Manzak, Özlem Demirbaş, Yasemin Yıldız, Murat Teker
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Abstract

Colour is typically the initial pollutant identified in wastewater. Membrane separation represents a novel approach to separation processes, with expectations of supplanting many traditional separation systems. The aim of this study is to investigate polymer inclusion membranes (PIMs) consisting of tri octyl methyl ammonium chloride as the carrier, tributylphosphate as the modifier, poly-vinyl chloride as the base polymer and 2-Nitro phenyl pentyl ether as the plasticizer for removing an acid dye (Red Erionyl A-3G) from aqueous solution. The dye adsorption on the membrane surface and its transition to the stripping phase was achieved by placing the membrane between two glass cells. Changing the stripping solution ensured both adsorption on the membrane surface and the transfer of all the dye to the stripping stage. Using a mixture of 0.8 M salicylic acid and 0.8 M NaOH, along with stirring at 1000 rpm during the stripping phase, extraction efficiency reached 98% in the feed phase and 53% in the stripping phase. When 1 M NaOH solution was employed as the stripping solution, the membrane absorbed all the dye within 10 minutes, but there was no transition to the stripping phase. The membrane has a durability of 2 days.

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酸性染料通过聚合物包涵膜与敌草快 336 和 TBP 的吸附和传输
颜色通常是废水中的初始污染物。膜分离是分离过程的一种新方法,有望取代许多传统分离系统。本研究的目的是研究由三辛基甲基氯化铵为载体、三丁基磷酸酯为改性剂、聚氯乙烯为基础聚合物、2-硝基苯基戊基醚为增塑剂组成的聚合物包涵膜(PIMs)从水溶液中去除酸性染料(红色 Erionyl A-3G)。通过将膜置于两个玻璃池之间,实现了染料在膜表面的吸附及其向剥离阶段的过渡。改变剥离溶液可确保染料在膜表面的吸附和全部转移到剥离阶段。使用 0.8 M 水杨酸和 0.8 M NaOH 的混合物,并在汽提阶段以 1000 rpm 的转速搅拌,进料阶段的萃取效率达到 98%,汽提阶段的萃取效率达到 53%。当使用 1 M NaOH 溶液作为剥离液时,膜在 10 分钟内吸收了所有染料,但没有过渡到剥离阶段。膜的耐久性为 2 天。
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来源期刊
Water, Air, & Soil Pollution
Water, Air, & Soil Pollution 环境科学-环境科学
CiteScore
4.50
自引率
6.90%
发文量
448
审稿时长
2.6 months
期刊介绍: Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments. Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation. Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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