White Light Emission from Dy3+-Activated CaY2O4 Phosphor

Abstract

Synthesis and characterization of a Dy³⁺-activated calcium yttrium oxide (CaY₂O₄) phosphor are reported. The CaY₂O₄:Dy³⁺ (1.5 mol%) phosphor is synthesized using a modified solid-state reaction technique for calcination and sintering. The cubic structure is revealed by the X-ray diffraction technique. The morphology and particle size distribution of the prepared phosphor are investigated by the FEGSEM technique. The chemical bonds and functional group analysis are confirmed by the FTIR. A photoluminescence analysis of the CaY₂O₄:Dy³⁺ phosphor shows dual excitation wavelengths at 285 and 348 nm, especially in the ultraviolet region. At 383 nm, three distinct emission peaks are found at the wavelengths 238, 485, and 571 nm. The spectroscopic parameters are calculated using the CIE chromaticity coordinates. The CIE coordinates of the Dysprosium ion-activated CaY₂O₄ phosphor (1.5 mol%) show an emission near the white light region of the chromaticity diagram, suggesting that it is suitable for W-LED applications.