Harapriya Rath, Manik Jana, Gunasekaran Velmurugan, Peter Comba
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引用次数: 0
Abstract
Rational synthesis, spectroscopic and solid-state structural isolation of an unprecedented core modified N-confused fused porphyrinogen 7 as a single isomer has been achieved in near quantitative yield. The solid-state crystal structure reveals a non planar structure as a result of four sp3 meso carbons for 7. All possible stereoisomers of the S2N3 hybrid N-confused fused porphyrinogen 7 have been unravelled via thorough DFT studies. The genesis of the porphyrinogen-porpho(mono/di)methene-porphyrin skeleton rearrangements have been unravelled via controlled chemical oxidation methods. The and (anti)aromaticity of the porphyrinoids 9 and 10 have been thoroughly investigated via spectroscopic and in-depth DFT studies.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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