Investigation of the role of yttrium sesquioxide nanoparticles on the properties of zinc oxide ceramics

Mônica Pereira Soares, Girija Atrey, Prasun Banerjee and Adolfo Franco Junior
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Abstract

In this work, zinc oxide (ZnO) ceramics were synthesized containing 0-5wt% of cubic yttrium sesquioxide (Y2O3) nanoparticles with solid state sintering technique at 1150°C. The secondary phase of Y2O3 did not enter into the crystalline zinc oxide. The Y2O3 acts as an inhibitor of grain growth. The absorption of the free charge carriers by the Y2O3 phase influences the infrared transmissions. The minimization of the phase mismatch while transferring the electric signal caused lower losses when Y2O3 was added to the zinc oxide matrices. The presence of the cubic sesquioxide at the grain boundary contributes to the interfacial polarization at lower frequencies when an alternating field is applied to the ceramics. These properties are anticipated to show a wider range of physical, optical and dielectric properties of ZnO: Y ceramics for optoelectronic applications.
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研究纳米二氧化钇对氧化锌陶瓷性能的影响
这项研究采用固态烧结技术,在 1150°C 下合成了含有 0-5wt% 立方倍半氧化钇(Y2O3)纳米颗粒的氧化锌(ZnO)陶瓷。Y2O3 的次生相没有进入结晶氧化锌中。Y2O3 起到了抑制晶粒生长的作用。Y2O3 相对自由电荷载流子的吸收会影响红外线的透过率。在氧化锌基质中加入 Y2O3 后,电信号传输过程中的相位失配最小化,从而降低了损耗。当交变磁场作用于陶瓷时,晶界上立方倍半二氧化物的存在有助于在较低频率下产生界面极化。预计这些特性将显示出 ZnO: Y 陶瓷在光电应用中更广泛的物理、光学和介电特性。
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