Liquid crystals from curved colloidal rods: waves, twists and more.

Abstract

The curvature of elongated microscopic building blocks plays a crucial role on their self-assembly into orientationally ordered phases. While rod-like molecules form a handful of liquid crystal (LC) phases, curved or banana-shaped molecules show more than fifty phases, with fascinating physical properties, such as chirality or polarity. Despite the fundamental and technological importance of these so-called 'banana-shaped liquid crystals', little is known about their microscopic details at the single-molecule level. Curved colloidal liquid crystals-liquid crystals formed by curved colloidal rods-are excellent model systems to optically resolve the structure and dynamics of curved building blocks within these condensed phases. Recent advances in the synthesis of curved rod-like particles have unlocked the potential for studying-at the single-particle level-the intimate relationship between shape and phase symmetry, and even confirmed the stability of elusive LC phases. Further developments in this nascent field promise exciting findings, such as the first observation of the colloidal twist-bend nematic phase or the fabrication of functional materials with curvature-dependent properties. In this Report on Progress, we will highlight recent advances in the synthesis and assembly of curved colloidal liquid crystals and discuss the upcoming challenges and opportunities of this field.