Composite Materials Based on Polypropylene and Carbon Nanofillers Obtained by in Situ Polymerization

IF 1.6 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series C Pub Date : 2024-07-12 DOI:10.1134/S1811238224600125
P. M. Nedorezova, A. N. Klyamkina, O. M. Palaznik, V. G. Shevchenko
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Abstract

A brief review of research initiated by works carried out earlier under the guidance of N.S. Enikolopov on the production of composite materials based on polypropylene and nanocarbon fillers by in situ polymerization is provided. The data on the mechanical, thermal, and electrical properties of the resulting materials are presented. The structure and concentration of nanofillers, as well as the structure of polypropylene (iso-, syndio-, and stereoblock), have a significant impact on the characteristics of the composites. The introduction of carbon nanofillers into the polypropylene matrix leads to a noticeable increase in the thermal and thermo-oxidative stability of the material. The prospects for using nanocomposites based on polypropylene and nanotubes and graphene nanoplatelets to develop shields and absorbers of electromagnetic radiation are considered. It has been shown that the modification of polypropylene properties by introducing various types of carbon nanofillers using in situ polymerization makes it possible to design novel functional composite materials with a valuable set of properties.

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基于聚丙烯和碳纳米填料的原位聚合复合材料
摘要 本文简要回顾了在 N.S. Enikolopov 的指导下,通过原位聚合生产基于聚丙烯和纳米碳填料的复合材料的研究工作。文中介绍了所生产材料的机械、热和电性能数据。纳米填料的结构和浓度以及聚丙烯的结构(异构、联体和立体嵌段)对复合材料的特性有重大影响。在聚丙烯基体中引入纳米碳填料可显著提高材料的热稳定性和热氧化稳定性。研究还探讨了使用基于聚丙烯、纳米管和石墨烯纳米片的纳米复合材料开发电磁辐射屏蔽和吸收器的前景。研究表明,利用原位聚合法引入各种类型的碳纳米填料来改变聚丙烯的特性,可以设计出具有一系列宝贵特性的新型功能复合材料。
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来源期刊
Polymer Science, Series C
Polymer Science, Series C 工程技术-高分子科学
CiteScore
3.00
自引率
4.50%
发文量
21
审稿时长
>12 weeks
期刊介绍: Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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