Enhanced thermal insulation behavior of metakaolin-based geopolymer reinforced by miscanthus fibers

IF 5.3 2区 地球科学 Q2 CHEMISTRY, PHYSICAL Applied Clay Science Pub Date : 2024-07-18 DOI:10.1016/j.clay.2024.107496
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Abstract

This study addresses the urgent demand for sustainable building materials, presenting a pioneering use of miscanthus fibers (MF) in metakaolin-based geopolymer paste for thermal insulation. Investigating metakaolin types, alkaline solutions, and curing methods, the study assesses workability, density, compressive strength, thermal properties, porosity, and microstructure. With 30 wt% MF, compressive strength reduces from 19.38 MPa to 6.43 MPa at 28 days, with porosity increasing from 37% to 52%. This heightened porosity, especially in pores >10 μm, lowers thermal conductivity, crucial for insulation. The geopolymer matrix without MF exhibits a thermal conductivity of 0.45 W.m−1.K−1, serving as a reference. A 50 wt% MF formulation achieves the lowest thermal conductivity (0.21 W.m−1.K−1) and 5 MPa compressive strength. Aligning with plastering, rendering, and masonry mortar standards, using Argical 1000 metakaolin enhances compressive strength by 57% compared to the reference sample made with Argicem metakaolin. Analytical Scanning Electron Microscopy reveals robust fiber-matrix adhesion, ensuring structural integrity.

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用马齿苋纤维增强偏高岭土基土工聚合物的隔热性能
本研究针对可持续建筑材料的迫切需求,介绍了在偏高岭土基土工聚合物浆料中使用马齿苋纤维(MF)进行隔热的开创性应用。研究调查了偏高岭土类型、碱性溶液和固化方法,评估了可加工性、密度、抗压强度、热性能、孔隙率和微观结构。30 wt% 的偏高岭土在 28 天时的抗压强度从 19.38 兆帕降低到 6.43 兆帕,孔隙率从 37% 增加到 52%。孔隙率的增加,尤其是 10 μm 的孔隙,降低了对隔热至关重要的导热性。不含 MF 的土工聚合物基体的导热系数为 0.45 W.m-1.K-1,可作为参考。50 wt% MF 配方的导热系数最低(0.21 W.m-1.K-1),抗压强度为 5 兆帕。与抹灰、渲染和砌筑砂浆标准一致,与使用 Argicem 偏高岭土制成的参考样品相比,使用 Argical 1000 偏高岭土可将抗压强度提高 57%。扫描电子显微镜分析表明,纤维与基质之间的粘附力很强,从而确保了结构的完整性。
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来源期刊
Applied Clay Science
Applied Clay Science 地学-矿物学
CiteScore
10.30
自引率
10.70%
发文量
289
审稿时长
39 days
期刊介绍: Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as: • Synthesis and purification • Structural, crystallographic and mineralogical properties of clays and clay minerals • Thermal properties of clays and clay minerals • Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties • Interaction with water, with polar and apolar molecules • Colloidal properties and rheology • Adsorption, Intercalation, Ionic exchange • Genesis and deposits of clay minerals • Geology and geochemistry of clays • Modification of clays and clay minerals properties by thermal and physical treatments • Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays) • Modification by biological microorganisms. etc...
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