Synthesis and Phase Formation in Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, Co) Oxide Ceramics Having Controllable Magnetic and Optical Properties

IF 1.5 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Inorganic Chemistry Pub Date : 2024-07-17 DOI:10.1134/S0036023623603276
A. V. Fedorova, A. A. Selyutin, N. A. Medzatyi
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Abstract

Ceramic Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, or Co) samples with perovskite structure were prepared by ordinary solid-phase technology. Phase formation in the prepared samples was investigated, and their unit cell parameters were determined by X-ray powder diffraction. Magnetic and optical properties of the samples were investigated by magnetic susceptibility measurements and diffuse reflectance spectroscopy. The phase composition, magnetic and optical properties were found to depend on the nature of the doped paramagnetic element.

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具有可控磁性和光学特性的 Ba_0.9Ca_0.1Zr_0.05M_0.10Ti_0.85O_3(M = Mn、Fe、Co)氧化物陶瓷的合成与相形成
采用普通固相法制备了具有钙钛矿结构的Ba0.9Ca0.1Zr0.05M0.10Ti0.85O3 (M = Mn, Fe, or Co)陶瓷样品。研究了制备样品的相形成,并通过x射线粉末衍射测定了样品的晶胞参数。通过磁化率测量和漫反射光谱研究了样品的磁性和光学性质。发现其相组成、磁性和光学性质取决于所掺杂顺磁元件的性质。
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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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