EPR Spectroscopy of the Ground Electron State of the Fe2+ Impurity Ion in Amethyst

IF 1.1 4区 物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Applied Magnetic Resonance Pub Date : 2024-07-16 DOI:10.1007/s00723-024-01683-7
V. F. Tarasov, R. B. Zaripov
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Abstract

Properties of two lowest electron levels of the Fe2+ impurity ion in a natural amethyst are studied by continuous wave electron paramagnetic resonance spectroscopy in the Q-band. It is established that the these levels present quasi-doublet \(\left| { \pm 2} \right\rangle\)with zero-field splitting of 30.9 ± 0.2 GHz. Orientation of principal magnetic axes and value of g-factor of this paramagnetic center are determined.

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紫水晶中 Fe2+ 杂质离子地面电子态的 EPR 光谱分析
通过 Q 波段连续波电子顺磁共振光谱研究了天然紫晶中 Fe2+ 杂质离子的两个最低电子水平的性质。结果表明,这两个电子层呈现出准双态(\left| { \pm 2} \right/rangle/),零场分裂为 30.9 ± 0.2 GHz。确定了这个顺磁中心的主磁轴方向和 g 因子值。
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来源期刊
Applied Magnetic Resonance
Applied Magnetic Resonance 物理-光谱学
CiteScore
1.90
自引率
10.00%
发文量
59
审稿时长
2.3 months
期刊介绍: Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
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