Study on Chemical Kinetic Mechanism and Autoignition Characteristics of Isopentanol/Gasoline Surrogate Fuel

Shuo Zhang, Xinghan Suo, Leilei Liu, Lin Wang, Hongqing Feng, Changhui Wang
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Abstract

In this paper, the detailed mechanism of isopentanol was simplified by DRGEP, generation rate analysis, reaction path optimisation and sensitivity analysis, and a comprehensive simplified mechanism of isopentanol/gasoline alternative fuels was obtained. isopentanol/gasoline characterised fuels with different blending ratios were investigated, and the results showed that blending of isopentanol promoted the autoignition of gasoline. It was found that blending isopentanol does not significantly affect the low-temperature reaction path of alkanes, but increases the reaction path flux from toluene to benzene. During combustion of isopentanol/gasoline alternative fuels, the isopentanol component exhibits a unique two-stage combustion phenomenon.
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异戊醇/汽油代用燃料的化学动力学机理和自燃特性研究
本文通过DRGEP、生成率分析、反应路径优化和敏感性分析,简化了异戊醇的详细机理,得到了异戊醇/汽油替代燃料的综合简化机理。研究了不同掺混比的异戊醇/汽油特性燃料,结果表明掺混异戊醇促进了汽油的自燃。研究发现,掺入异戊醇不会明显影响烷烃的低温反应路径,但会增加从甲苯到苯的反应路径通量。在异戊醇/汽油替代燃料的燃烧过程中,异戊醇成分表现出独特的两阶段燃烧现象。
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