Performance of geopolymer paste under the different NaOH solution concentrations

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-07-09 DOI:10.1680/jmacr.24.00069
Tao Wang, Xiangqian Fan, Changsheng Gao, Chiyu Qu
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Abstract

With the characteristics of low carbon, environmental protection, energy saving, and emission reduction, geopolymer pastes can effectively alleviate environmental and economic problems caused by the construction materials industry. The mechanical properties of geopolymer pastes are greatly affected by the composition of alkaline activators, while the existing research on their influence rules is not uniform. This study investigated the effects of alkaline activators composed of varying concentrations of NaOH solution under standard curing conditions on the mechanical properties and material characteristics of fly ash and slag-based geopolymer pastes. The results of the study indicated that under standard curing conditions, the mechanical properties of geopolymer pastes increased with the increase of NaOH solution concentration in alkaline activators. Under the influence of alkaline activators with 16 M NaOH solution, the flexural strength and compressive strength of geopolymer pastes reached the highest values at 28 d, up to 5.43 MPa and 39.13 MPa, respectively. Increasing the NaOH solution concentration in alkaline activators can promote the production of gel products such as N-A-S-H, forming a dense microstructure with a lower porosity, leading to higher mechanical properties.
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不同 NaOH 溶液浓度下土工聚合物浆料的性能
土工聚合物浆料具有低碳、环保、节能、减排等特点,可有效缓解建筑材料行业带来的环境和经济问题。土工聚合物浆料的力学性能受碱性活化剂组成的影响较大,而现有研究对其影响规律的研究并不统一。本研究探讨了在标准固化条件下,由不同浓度的 NaOH 溶液组成的碱性活化剂对粉煤灰和矿渣基土工聚合物浆料的力学性能和材料特性的影响。研究结果表明,在标准固化条件下,土工聚合物浆料的机械性能随着碱性活化剂中 NaOH 溶液浓度的增加而提高。在含有 16 M NaOH 溶液的碱性活化剂的影响下,土工聚合物浆料的抗折强度和抗压强度在 28 d 时达到最高值,分别为 5.43 MPa 和 39.13 MPa。提高碱性活化剂中的 NaOH 溶液浓度可促进 N-A-S-H 等凝胶产品的生产,形成孔隙率较低的致密微结构,从而获得更高的机械性能。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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