Stable Isotopes of Landfast Sea Ice as a Record of La Grande River Under-Ice Plume Dispersal

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-07-08 DOI:10.1139/as-2024-0003
Aura Diaz, Zou zou Kuzyk, A. Guzzi, Kaushik Gupta, T. Papakyriakou, Jens Ehn
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Abstract

Vertical profiles of salinity, and isotopic abundance ratios of hydrogen (δ2H ) and oxygen (@delta;18O) of 18 landfast ice cores, collected along the northeast coast of James Bay in March 2019, and one ice core collected in Belcher Islands, were used to obtain the winter timeseries of the spatiotemporal evolution of the under-ice plume of La Grande River (LGR), the dominant river in the area. Variability in the isotopic composition and salinity of the ice cores indicated changes to the water source composition at the ice-water interface when the ice layers formed. The increased presence of river water beneath the ice during January-March was marked by more negative isotopic ratios in the lower portion of the ice as river discharge was increased for hydroelectric production. River water was the source of ~43% of the ice in our ice core samples (n=320) with the interquartile range from 16% to 71%. The river water fractions incorporated into the ice indicate that LGR under-ice plume extended more than 75 km north and at least 30 km south of the river mouth for ~3 months. These findings correspond well with more challenging to obtain hydrographic observations. End-of-winter ice core sampling and analysis for isotopic abundance has potential as a tool to monitor dispersal of LGR discharge into the ice-covered coastal environment.
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作为拉格兰德河冰下羽流散布记录的陆地海冰稳定同位素
利用2019年3月沿詹姆斯湾东北海岸采集的18块陆地冰芯和在贝尔彻群岛采集的1块冰芯的盐度垂直剖面以及氢(δ2H)和氧(@delta;18O)同位素丰度比,获得了该地区主要河流拉格兰德河(LGR)冰下羽流的冬季时空演变序列。冰芯同位素组成和盐度的变化表明,冰层形成时冰水界面的水源组成发生了变化。1 月至 3 月期间,冰层下的河水增多,其特征是冰层下部的负同位素比值增加,因为水电生产需要增加河水排放量。在我们的冰芯样本(n=320)中,约 43% 的冰来源于河水,其四分位数范围为 16% 至 71%。冰中的河水成分表明,LGR 冰下羽流向北延伸了 75 千米以上,向南延伸了至少 30 千米,距河口约 3 个月。这些发现与较难获得的水文观测结果非常吻合。在冬季结束时进行冰芯取样和同位素丰度分析,有可能成为监测 LGR 向冰覆盖沿岸环境排放扩散情况的一种手段。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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