LASER-ASSISTED SYNTHESIS OF WATER COLLOIDAL METALLIC NANOCOMPOSITES

N. Stankova, Anna Dikovska, M. Koleva, N. Nedyalkov, A. Nikolov, Dimitar Dimov, Daniela Karashanova
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Abstract

Picosecond and Nanosecond Nd:YAG laser systems with a fundamental wavelength of 1064 nm are utilizedfor green synthesis of bimetallic nanocomposites based on metal combinations of Pt/Ti, Pd/Ti, Pt/Zn and Pd/Zn. The laser assisted method is based on pulsed laser ablation of metal targets, which are immersed consecutively in bidistilled water to obtain water colloids of the corresponding bimetallic nanostructures. Comparative study of the structural and optical properties of the nanocomposites is conducted by means of transmission electron microscopy in its corresponding main modes and by optical spectrometer measurements, respectively. Suspensions of water colloids of the nanocomposites and methylene blue dye prepared in 1 : 2.5 ratio, respectively, are exposed under sunlight irradiation for 3 h. Photocatalytic activity of the nanocomposites against methylene blue (MB) dye is tested by measuring the optical absorbance of the suspensions before and after the sunlight irradiation.
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激光辅助合成水胶体金属纳米复合材料
利用基本波长为 1064 nm 的皮秒和纳秒 Nd:YAG 激光系统绿色合成了基于 Pt/Ti、Pd/Ti、Pt/Zn 和 Pd/Zn 金属组合的双金属纳米复合材料。激光辅助法是基于脉冲激光烧蚀金属靶,然后将金属靶连续浸入双蒸水中,以获得相应双金属纳米结构的水胶体。通过相应主要模式的透射电子显微镜和光学光谱仪测量,分别对纳米复合材料的结构和光学特性进行了比较研究。将纳米复合材料的水胶体和亚甲基蓝染料分别以 1 : 2.5 的比例制备成悬浮液,在太阳光下照射 3 小时,通过测量悬浮液在太阳光照射前后的吸光度,测试纳米复合材料对亚甲基蓝(MB)染料的光催化活性。
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Journal of Chemical Technology and Metallurgy
Journal of Chemical Technology and Metallurgy Engineering-Industrial and Manufacturing Engineering
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1.40
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