SYNTHESIS AND DEICING PERFORMANCE OF CALCIUM MAGNESIUM ACETATE FROM DOLOMITIC LIMESTONE OF ABBOTABAD REGION, PAKISTAN

Asma Yamin, W. Rehman, Amin Ur Rahman, Ibrar Ahmed, Muhammad Siddique Afridi
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Abstract

Calcium Magnesium Acetate (CMA) has recently gained much popularity due to its emerging applications in road deicing, and as an industrial adsorbent for removal of Hydrogen Sulfide (H2S) gas and other odorous acid gases from gaseous streams. CMA is a multi-purpose, low-corrosion and concrete-safe alternative to the conventionally used sodium chloride (NaCl) deicers. CMA prevents snow and ice from bonding to either surfaces or itself. In the present study, CMA was prepared from dolomitic limestone of Abbottabad region, Pakistan. The prepared samples were characterized through various instrumental techniques like Scanning Electron Microscopy combined with Energy Dispersive X-Ray (SEM-EDX), X-Ray Diffraction (XRD), and Fourier Transform Infra-Red Spectroscopy (FT-IR).The performance of CMA was compared with NaCl. It was found that after 24 hours, 15 %, of ice melted, when no deicing agent was used. Likewise, 49.4 %, and 66.4 % of ice melted, when CMA and NaCl were used as deicing agents, respectively. Thus, the rate of ice melting increased by 70 % and 77.4 %, with CMA and NaCl respectively. The analysis showed that CMA could successfully be produced from dolomitic limestone of Abbottabad, and the same may be applied for deicing applications.
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巴基斯坦阿博塔巴德地区白云质石灰石中醋酸钙镁的合成和除冰性能
醋酸镁钙 (CMA) 最近因其在道路除冰中的新兴应用以及作为工业吸附剂去除气流中的硫化氢 (H2S) 气体和其他有异味的酸性气体而大受欢迎。CMA 是一种多用途、低腐蚀性、对混凝土安全的除冰剂,可替代传统使用的氯化钠(NaCl)除冰剂。CMA 可防止冰雪粘附到表面或自身。本研究采用巴基斯坦阿伯塔巴德地区的白云质石灰石制备 CMA。通过各种仪器技术,如扫描电子显微镜结合能量色散 X 射线(SEM-EDX)、X 射线衍射(XRD)和傅立叶变换红外光谱(FT-IR),对制备的样品进行了表征。结果发现,24 小时后,在不使用除冰剂的情况下,15% 的冰融化了。同样,当使用 CMA 和氯化钠作为除冰剂时,分别有 49.4% 和 66.4% 的冰融化。因此,使用 CMA 和氯化钠后,融冰率分别提高了 70% 和 77.4%。分析表明,可以成功地从阿伯塔巴德的白云质石灰石中生产出 CMA,并可将其用于除冰用途。
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Journal of Chemical Technology and Metallurgy
Journal of Chemical Technology and Metallurgy Engineering-Industrial and Manufacturing Engineering
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1.40
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