Poly[[μ3-2-(benzotriazol-1-yl)acetato-κ3O:O′:N3]chlorido­(ethanol-κO)cobalt(II)]

IUCrData Pub Date : 2024-07-01 DOI:10.1107/S2414314624006308
Yun-Yun Zheng , De-Sen Su , Qing-Hua Yao , Min-Min Huang
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Abstract

The reaction of 2-(benzotriazol-1-yl) acetic acid with CoCl2 at room temperature in ethanol generates the title three-dimensional cobalt-based coordination polymer.

In the title compound, [Co(C8H6N3O2)Cl(C2H5OH)]n, the CoII atoms adopt octa­hedral trans-CoN2O4 and tetra­hedral CoCl2O2 coordination geometries (site symmetries

and m, respectively). The bridging μ3-O:O:N 2-(benzotriazol-1-yl)acetato ligands connect the octa­hedral cobalt nodes into (010) sheets and the CoCl2 fragments link the sheets into a tri-periodic network. The structure displays O—H⋯O hydrogen bonding and the ethanol mol­ecule is disordered over two orientations.
  1. Download: Download high-res image (382KB)
  2. Download: Download full-size image

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聚[[μ3-2-(苯并三唑-1-基)乙酸酯-κ3 O:O′:N 3]氯化(乙醇-κO)钴(II)
在标题化合物[Co(C8H6N3O2)Cl(C2H5OH)] n 中,CoII 原子采用八面体反式-CoN2O4 和四面体 CoCl2O2 配位几何结构(位点对称性分别为 \overline{1} 和 m)。桥接的 μ3-O:O:N 2-(苯并三唑-1-基)乙酸配体将八面体钴节点连接成 (010) 片,而 CoCl2 片段则将这些片连接成一个三周期网络。该结构显示出 O-H...O 氢键,乙醇分子在两个方向上是无序的。
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3-(2-Hy-droxy-eth-yl)-1-(4-nitro-phen-yl)-1H-imidazol-3-ium bromide. 4'-(2-Meth-oxy-phen-yl)-2,2':6',2''-terpyridine. 3,5,6-Tri-chloro-pyridin-2-ol. 4-Amino-3,5-di-chloro-pyridine. Bis(azido-κN 1)bis-(2,2'-di-pyridyl-amine-κ2 N 1,N 1')iron(II) monohydrate.
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