The Use of Nonmetallic Fraction Particles with the Double Purpose of Increasing the Mechanical Properties of Low-Density Polyethylene Composite and Reducing the Pollution Associated with the Recycling of Metals from E-Waste

IF 5.5 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-07-03 DOI:10.3390/recycling9040056
R. Flores-Campos, R. Deaquino-Lara, Mario Rodríguez-Reyes, R. Martínez-Sánchez, Rosa Hilda Estrada-Ruiz
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Abstract

A restorative process, where the nonmetallic fraction from e-waste printed circuit boards is reused as a raw material for the conformation of a new polymer matrix composite with increased properties favoring its industrial applications, is proposed with a zero residues approach. Low density polyethylene pellets and nonmetallic fraction particles were mixed, and due to the generation of static electricity during the mixing process, the nonmetallic particles became attached to the polyethylene pellets; the blended material was fed into a screw extruder, producing filaments of the new composite. Mechanical properties increased as the particles content increased, presenting an ultimate tensile strength going from 20 for the raw low-density polyethylene to more than 60 MPa, and a yield strength that goes from 10 to 50 MPa on the composite with 6.0 wt.% particles. Also, the flammability of the composite improved, reducing its linear burning rate and increasing the time between detachment of two consecutive drops. Nonmetallic fraction particles were oriented in the extrusion direction and had a good adhesion with the polyethylene matrix. These composites can be employed for the production of prototypes using additive manufacture.
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使用非金属馏分微粒具有双重目的:提高低密度聚乙烯复合材料的机械性能和减少从电子垃圾中回收金属所造成的污染
我们提出了一种零残留的修复工艺,将电子废弃物印刷电路板中的非金属部分作为原材料重新利用,以形成一种新的聚合物基复合材料,这种复合材料具有更高的性能,有利于其工业应用。将低密度聚乙烯颗粒和非金属馏分颗粒混合,由于混合过程中产生静电,非金属颗粒附着在聚乙烯颗粒上;将混合材料送入螺杆挤压机,生产出新型复合材料丝。随着颗粒含量的增加,机械性能也随之提高,原始低密度聚乙烯的极限拉伸强度从 20 兆帕提高到 60 兆帕以上,颗粒含量为 6.0 wt.% 的复合材料的屈服强度从 10 兆帕提高到 50 兆帕。此外,复合材料的可燃性也得到了改善,降低了线性燃烧速率,延长了连续两滴之间的分离时间。非金属馏分颗粒在挤压方向上定向,与聚乙烯基体有良好的粘附性。这些复合材料可用于使用添加剂制造原型。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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