On the Theory of Dynamic Susceptibility of Soft Magnetic Colloids

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL Colloid Journal Pub Date : 2024-07-15 DOI:10.1134/s1061933x24600246
A. Yu. Zubarev, L. Yu. Iskakova, A. Yu. Musikhin
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Abstract

The magnetization reversal kinetics has been theoretically considered for a nanosized ferromagnetic particle in a soft viscoelastic medium. In contrast to well-known works, we have considered the simultaneous action of the Néel mechanism of magnetization reversal of a particle (overcoming the potential barrier of magnetic anisotropy by its magnetic moment), and rotation (turn) of the particle body as a result of a change in the external magnetic field. The case of a high magnetic anisotropy of the particle is considered, i.e., it has been assumed that its energy significantly exceeds the thermal energy of the system and the energy of the interaction between the particle and the magnetic field. No other limitations have been imposed on field strength. The case of low fields has been considered in greater detail in the linear approximation of the dependence of magnetization on the field. The components of the complex susceptibility of the composite are calculated within the framework of this approximation. It has been shown that the real component of the susceptibility decreases monotonically with the field frequency. If the stiffness of the composite is high or low, the imaginary component has one maximum, which corresponds to the Néel mechanism of magnetization reversal or particle rotation in a viscoelastic medium, respectively. At intermediate values of composite stiffness, the frequency dependence of the imaginary susceptibility has two maxima.

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论软磁胶体的动态感应性理论
摘要 从理论上研究了软粘弹性介质中纳米级铁磁粒子的磁化反转动力学。与众所周知的工作不同,我们考虑了粒子磁化反转的奈尔机制(通过其磁矩克服磁各向异性的势垒)和粒子体因外部磁场变化而旋转(转向)的同时作用。我们考虑了粒子的高磁各向异性情况,即假设粒子的能量大大超过系统的热能以及粒子与磁场之间相互作用的能量。磁场强度没有其他限制。在磁化与磁场的线性近似关系中,我们更详细地考虑了低磁场的情况。在此近似的框架内计算了复合材料的复感性分量。结果表明,磁感应强度的实分量随磁场频率单调递减。如果复合材料的刚度较高或较低,则虚分量有一个最大值,分别对应于粘弹性介质中的磁化反转或粒子旋转的奈尔机制。在复合材料刚度的中间值,虚电感的频率依赖性有两个最大值。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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