Fe3O4/PANI/CuI as a sustainable heterogeneous nanocatalyst for A3 coupling†

Abstract

The prepared copper iodide nanoparticles were impregnated on the support of ferrite nanoparticles functionalized with polyaniline, resulting in a magnetically recoverable heterogeneous nanocomposite. The activity of the prepared nanocomposite was investigated in the synthesis of propargylamine derivatives via A³ coupling under mild conditions. Techniques such as FESEM, EDAX, XRD, XPS, TEM, BET and FTIR were used to characterize the effective and unique heterogeneous Fe₃O₄/PANI/CuI nanocomposite developed in this work. This method used in the current study has several advantages, including a short reaction time, neat conditions, good product yield, ideal green matrices values, reusability for up to seven cycles, and magnetic retrievability.