Effect of Heat Treatment and Pigment Fraction on the Thermal Conductivity and Dynamic Behavior of Poly (Methyl Methacrylate) Pigmented with Titanium Dioxide

IF 0.9 4区 材料科学 Q4 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Russian Journal of Nondestructive Testing Pub Date : 2024-07-27 DOI:10.1134/s1061830923601423
N. Ghebrid, D. Dadache, B. Barka, M. Guellal, F. Rouabah, M. Fois
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Abstract

The thermal behavior of a poly(methylmethacrylate) (PMMA) pigmented with titanium dioxide (TiO2) is studied in both Steady state and transient regimes in the present work. The numerical results of thermal conductivity, based on the finite element method, are compared to theoretical models and experimental measurements, which varies depending on the quenching temperature and pigment content. Time evolution of temperatures during the quenching of the composite is taken into account for different quenching temperatures and different pigment contents. It is noted that the heat exchange becomes slower for a pigment fraction of 0.5%, and the steady state is reached more rapidly for higher pigment content. The AFM image of the PMMA/TiO2 composite with content equal to 3% of titanium dioxide. This demonstrates a good distribution of the particles throughout the matrix, with the individual particles being uniformly dispersed and securely embedded in the polymer matrix, thereby avoiding any clustering. An improvement in heat exchange is observed in the composite with a high content of titanium dioxide. This improvement is attributed to the increase in the thermal conductivity of the PMMA/TiO2 composite.

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热处理和颜料组分对二氧化钛颜料聚(甲基丙烯酸甲酯)导热性和动态行为的影响
摘要 本研究对添加了二氧化钛(TiO2)颜料的聚(甲基丙烯酸甲酯)(PMMA)在稳态和瞬态下的热行为进行了研究。基于有限元法得出的导热系数数值结果与理论模型和实验测量结果进行了比较。针对不同的淬火温度和不同的颜料含量,考虑了复合材料淬火过程中温度的时间演变。结果表明,当颜料含量为 0.5% 时,热交换速度变慢,而颜料含量越高,达到稳定状态的速度越快。二氧化钛含量等于 3% 的 PMMA/TiO2 复合材料的原子力显微镜图像。这表明颗粒在整个基体中分布良好,单个颗粒均匀分散并牢固地嵌入聚合物基体中,从而避免了任何团聚现象。在二氧化钛含量较高的复合材料中可以观察到热交换的改善。这种改善归因于 PMMA/TiO2 复合材料热导率的提高。
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来源期刊
Russian Journal of Nondestructive Testing
Russian Journal of Nondestructive Testing 工程技术-材料科学:表征与测试
CiteScore
1.60
自引率
44.40%
发文量
59
审稿时长
6-12 weeks
期刊介绍: Russian Journal of Nondestructive Testing, a translation of Defectoskopiya, is a publication of the Russian Academy of Sciences. This publication offers current Russian research on the theory and technology of nondestructive testing of materials and components. It describes laboratory and industrial investigations of devices and instrumentation and provides reviews of new equipment developed for series manufacture. Articles cover all physical methods of nondestructive testing, including magnetic and electrical; ultrasonic; X-ray and Y-ray; capillary; liquid (color luminescence), and radio (for materials of low conductivity).
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