Analysis of the Influence of Borate and Fluoride Fluxes on the Sintering of Silicate Raw Materials

IF 0.6 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS Glass and Ceramics Pub Date : 2024-07-22 DOI:10.1007/s10717-024-00670-5
B. M. Gol’tsman, E. A. Yatsenko, Yu. A. Bostanov, A. E. Panteleeva, V. A. Smoliy, V. S. Yatsenko
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Abstract

The effectiveness of using borate (borax) and fluoride (sodium fluoride) fluxes in the sintering of crystalline (sand) and amorphous (diatomite) silicate raw materials was considered. The change in the density and appearance of samples with varying amounts of fluxes during their heat treatment at different temperatures was described. It was shown that the introduction of 4 wt.% of borax reduces the temperature necessary to reach a density of 1500 kg/m3 by 100°C, and 6 wt.% of borax by 200°C. It was shown that the introduction of fluxes increases the amount of x-ray amorphous glass phase due to depolymerization of the silicon-oxygen network and the formation of a low-temperature melt.

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硼酸盐和氟化物助熔剂对硅酸盐原料烧结的影响分析
研究了在结晶(砂)和无定形(硅藻土)硅酸盐原料烧结过程中使用硼酸盐(硼砂)和氟化物(氟化钠)助熔剂的效果。研究描述了在不同温度下进行热处理时,添加不同数量助熔剂的样品在密度和外观上的变化。结果表明,加入 4 wt.% 的硼砂后,达到 1500 kg/m3 密度所需的温度降低了 100°C,加入 6 wt.% 的硼砂后降低了 200°C。研究表明,由于硅氧网络的解聚和低温熔体的形成,助熔剂的引入增加了 X 射线无定形玻璃相的数量。
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来源期刊
Glass and Ceramics
Glass and Ceramics 工程技术-材料科学:硅酸盐
CiteScore
1.00
自引率
16.70%
发文量
85
审稿时长
6-12 weeks
期刊介绍: Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.
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