Recent advances in molybdenum catalyzed asymmetric organic transformations

IF 14 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Trends in Chemistry Pub Date : 2024-07-23 DOI:10.1016/j.trechm.2024.06.010
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Abstract

Transition metal-catalyzed asymmetric organic transformations are powerful tools for the syntheses of chiral building blocks, bioactive molecules, and natural products. Compared with noble transition metals, the development of chiral catalytic systems based on non-noble transition metals is appealing due to their lower cost and ready availability. Among those, the molybdenum complexes are ideal candidates as chiral metal catalysts for catalytic asymmetric organic transformations because of their ready availability and versatile reactivity. The past decades have witnessed advances in the development of chiral Mo-complexes and their application in catalytic asymmetric organic transformations. This review article summarizes the development of several types of chiral Mo-complexes and highlights recent advances in Mo-catalyzed asymmetric organic transformations.

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钼催化不对称有机转化的最新进展
过渡金属催化的不对称有机转化是合成手性构件、生物活性分子和天然产物的有力工具。与惰性过渡金属相比,基于非惰性过渡金属的手性催化系统因其成本较低且随时可用而备受青睐。其中,钼配合物因其随时可用性和多功能反应性,成为催化不对称有机转化的理想手性金属催化剂。过去几十年来,手性钼络合物的开发及其在催化不对称有机转化中的应用取得了长足的进步。这篇综述文章总结了几种手性钼络合物的发展,并重点介绍了钼催化不对称有机转化的最新进展。
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来源期刊
Trends in Chemistry
Trends in Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
28.00
自引率
0.60%
发文量
138
期刊介绍: Trends in Chemistry serves as a new global platform for discussing significant and transformative concepts across all areas of chemistry. It recognizes that breakthroughs in chemistry hold the key to addressing major global challenges. The journal offers readable, multidisciplinary articles, including reviews, opinions, and short pieces, designed to keep both students and leading scientists updated on pressing issues in the field. Covering analytical, inorganic, organic, physical, and theoretical chemistry, the journal highlights major themes such as biochemistry, catalysis, environmental chemistry, materials, medicine, polymers, and supramolecular chemistry. It also welcomes articles on chemical education, health and safety, policy and public relations, and ethics and law.
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