Scintillation and Luminescent Properties of the (Gd,Y)3Al2Ga3O12:Ce Ceramics Obtained by Compaction of Green Bodies Using Digital Light Processing 3D Printing

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-07-26 DOI:10.3390/photonics11080695
L. V. Ermakova, V. Smyslova, Valery V. Dubov, P. Karpyuk, Petr S. Sokolov, I. Komendo, A. Bondarau, Vitaly Mechinsky, Mikhail V. Korzhik
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Abstract

Dense and transparent ceramic samples of a (Gd,Y)3Al2Ga3O12:Ce scintillator were obtained by using stereolithography-based Digital Light Processing (DLP) 3D printing for compacting, subsequent burnout, and pressureless sintering. The effects of stoichiometric deviations and green body compaction methods (uniaxial pressing versus DLP 3D printing) on the optical, luminescent, and scintillation properties of ceramics were analyzed. An excess of Y and Gd in the composition led to an increase in transmittance and to the acceleration of the scintillation kinetics. Moreover, transparent ceramics made of 3D-printed green bodies were found to be superior in light yield to the samples, which were prepared from the same powders and densified by uniaxial pressing.
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利用数字光处理三维打印技术压制绿色体获得的(Gd,Y)3Al2Ga3O12:Ce 陶瓷的闪烁和发光特性
通过使用基于立体光刻技术的数字光处理(DLP)三维打印技术进行压制、后续烧结和无压烧结,获得了(Gd,Y)3Al2Ga3O12:Ce闪烁体的致密透明陶瓷样品。分析了化学计量偏差和绿色体压制方法(单轴压制与 DLP 三维打印)对陶瓷的光学、发光和闪烁特性的影响。成分中过量的 Y 和 Gd 会导致透射率增加和闪烁动力学加速。此外,还发现由三维打印绿色体制成的透明陶瓷在光产率方面优于由相同粉末制备并通过单轴压制致密的样品。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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