Standard Operating Procedure for the determination of trace elements in hydrothermal fluids by Inductively Coupled Plasma Mass Spectrometry (ICP-MS)

Monica Correggia, Luciano Di iorio, A. Bastianoni, Mustafa Yücel, A. Cordone, D. Giovannelli
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Abstract

This standard operating procedure (SOP) validates an inductively coupled plasma mass spectrometry (ICP-MS) procedure for the determination of trace elements in hydrothermal fluids. Hydrothermal fluids are aqueous solutions with a wide range of temperature, salinity, pH and trace elements that can be used by a set of microbial proteins containing redox-sensitive transition metals as their catalytic core. Due to the high variability of these samples, we have developed this protocol taking into account the special features of the matrices analyzed. An ICP-MS 7900 Agilent system was used. Calibration curves are linear in the 0.01 to 100 μg/L concentration range.
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利用电感耦合等离子体质谱法(ICP-MS)测定热液中痕量元素的标准操作程序
本标准操作程序(SOP)验证了测定热液中痕量元素的电感耦合等离子体质谱法(ICP-MS)程序。热液是一种水溶液,其温度、盐度、pH 值和痕量元素的范围很广,可以被一系列含有氧化还原敏感过渡金属作为催化核心的微生物蛋白质所利用。由于这些样品的变异性很高,我们在制定该方案时考虑到了所分析基质的特殊性。使用的是安捷伦公司的 ICP-MS 7900 系统。校准曲线在 0.01 至 100 μg/L 浓度范围内呈线性关系。
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