A novel composite la-conversion coatings for enhanced anti-corrosion performance under a harsh aqueous environment

IF 1.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Bulletin of the Chemical Society of Ethiopia Pub Date : 2024-07-12 DOI:10.4314/bcse.v38i5.20
Haewon Byeon, M. S. Sivagama Sundari, Ilango Karuppasamy, R. S. Jayaram
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Abstract

The ceramic lanthanum nanoparticles with uniformly dispersed spherical nanostructures were successfully synthesized using sonication-assisted synthesis. The morphologies and phase compositions were assessed and investigated. The electrochemical impedance analysis potentio-dynamic polarisation measurements were used to calculate the corrosion protection properties of prepared ceramic lanthanum nanoparticles. The La2O3 nanoparticles were added as a surface coating layer to enhance the corrosion resistance of low-carbon steel. The particles' impact on coating development, morphology, and corrosion inhibition efficacy were studied. After particle integration, results show a dramatic reduction in porosity and thickness, affecting corrosion resistance. Incorporating ceramic lanthanum nanoparticles into a coating reduces porosity and increases hardness, improving corrosion resistance; the result implies the suggested technique is viable for creating functionalized coatings on low-carbon-based materials. The results also demonstrated that these methods may increase the development and protectiveness of the coating. There was a crucial nano particulate La2O3 level at which the conversion coatings exhibited the best protective qualities. As it increased the corrosion potential and lowered the anodic current, the composite La-conversion coatings may offer substantial corrosion protection for prolonged immersion in a 3.5% NaCl solution. KEY WORDS: Ceramic nanoparticles, Low carbon steel, Corrosion prevention, Polarization Bull. Chem. Soc. Ethiop. 2024, 38(5), 1453-1468.                                                    DOI: https://dx.doi.org/10.4314/bcse.v38i5.20                                                      
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在恶劣水环境下增强防腐蚀性能的新型 La-conversion 复合涂料
利用超声辅助合成法成功合成了具有均匀分散球形纳米结构的陶瓷镧纳米粒子。对其形貌和相组成进行了评估和研究。电化学阻抗分析电位动态极化测量用于计算所制备的纳米镧陶瓷颗粒的腐蚀保护性能。添加 La2O3 纳米粒子作为表面涂层,可增强低碳钢的耐腐蚀性。研究了颗粒对涂层发展、形态和缓蚀效果的影响。结果表明,颗粒加入后,孔隙率和厚度显著降低,从而影响了耐腐蚀性。在涂层中加入陶瓷纳米镧粒子可降低孔隙率,增加硬度,从而提高耐腐蚀性;这意味着所建议的技术可用于在低碳材料上形成功能化涂层。结果还表明,这些方法可以提高涂层的发展和保护能力。在一个关键的纳米微粒 La2O3 水平上,转化涂层表现出最佳的保护性。由于提高了腐蚀电位并降低了阳极电流,La-转化复合涂层可在 3.5% NaCl 溶液中长期浸泡时提供实质性腐蚀保护。关键词: 陶瓷纳米颗粒 低碳钢 防腐 极化 Bull.Chem.Soc.2024, 38(5), 1453-1468. DOI: https://dx.doi.org/10.4314/bcse.v38i5.20
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来源期刊
CiteScore
2.20
自引率
8.30%
发文量
113
审稿时长
6-12 weeks
期刊介绍: The Bulletin of the Chemical Society of Ethiopia (BCSE) is a triannual publication of the Chemical Society of Ethiopia. The BCSE is an open access and peer reviewed journal. The BCSE invites contributions in any field of basic and applied chemistry.
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