Effects of V Addition on the Microstructure and Mechanical Properties of a PM Ti–4Al–3Cu–2Fe Alloy

Mojtaba Najafizadeh, Deliang Zhang, Mansoor Bozorg, Mehran Ghasempour-Mouziraji
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Abstract

The effects of an addition of 4 wt pct V on the mechanical properties and microstructure of a Ti–4Al–3Cu–2Fe (wt pct) alloy manufactured by extrusion of compacts of TiH2/Al/Cu/Fe powder blend followed by vacuum annealing were investigated. It was found that the V addition changed the microstructure of the alloy from lamellar structure to basket-wave structure, increased the volume fraction of β phase from 47 to 53 pct, and reduced the average α lamella thickness significantly from 4.0 to 1.5 μm. Surprisingly, these compositional and microstructural changes cause only a small increase of the yield stress (from 1132 to 1151 MPa) and elongation to fracture (from 6.1 to 6.5 pct), but the strain hardening rate of the alloys are substantially enhanced over a narrow strain range of 0.9-1.7 pct, leading to a clear increase of the ultimate tensile strength from 1184 to 1252 MPa. The main mechanism for the microstructural changes caused by the V addition is the enhanced stabilization of β phase by V atoms and the growth restriction of α lamellae by V partitioning between α and β phases. The enhancement of strain hardening rate can be attributed to the enhance the number density of the α/β interfaces associated with the decrease of the α lamella thickness and which provides more effective barriers for the movement of dislocations.

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添加 V 对 PM Ti-4Al-3Cu-2Fe 合金微观结构和力学性能的影响
研究了添加 4 wt pct V 对通过挤压 TiH2/Al/Cu/Fe 混合粉末压块然后真空退火制造的 Ti-4Al-3Cu-2Fe (wt pct) 合金的机械性能和微观结构的影响。研究发现,V 的添加使合金的微观结构从薄片结构变为篮波结构,β 相的体积分数从 47% 增加到 53%,平均 α 薄片厚度从 4.0 μm 显著减少到 1.5 μm。令人惊讶的是,这些成分和微观结构的变化仅导致屈服应力(从 1132 兆帕增加到 1151 兆帕)和断裂伸长率(从 6.1 百分比增加到 6.5 百分比)的小幅增加,但在 0.9-1.7 百分比的狭窄应变范围内,合金的应变硬化率却大幅提高,导致极限抗拉强度从 1184 兆帕明显提高到 1252 兆帕。添加 V 导致微观结构变化的主要机制是 V 原子增强了 β 相的稳定性,以及 V 在 α 和 β 相之间的分区限制了 α 片层的生长。应变硬化率的提高可归因于随着α薄片厚度的减小,α/β界面的数量密度增加,从而为位错运动提供了更有效的屏障。
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