Characteristics of Cenomanian–Turonian Oceanic Anoxic Event 2 and its Impact on Organic Carbon Accumulation in the Abu Roash (F) Organic-Rich Carbonate Rocks in the Abu Gharadig Field, Egypt

IF 2.9 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ACS Earth and Space Chemistry Pub Date : 2024-07-31 DOI:10.1021/acsearthspacechem.4c00002
Tamer E. Hamed, Mohammed Hail Hakimi, Naira M. Lotfy, Mohammad Alqudah, Ali Y. Kahal, Afikah Rahim, Emad A. Eysa
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Abstract

The Cenomanian–Turonian was a period of climatic perturbations associated with extraordinary marine production of organic carbon during the redox conditions in the southern Neo-Tethys Ocean. The Abu Roash-F carbonates in the northwestern desert of Egypt were deposited during this period. This work revealed some organic and inorganic geochemical results combined with microscopic examinations of the carbonate rocks of the mid-Cretaceous Abu Roash-F Member from two exploration wells in the Abu Gharadig Basin, Egypt. This work was designed to understand the paleoenvironmental conditions during Cenomanian–Turonian oceanic anoxic event 2 (OAE2) and its impact on the organic carbon-rich accumulation in Abu Roash (F) carbonates. Geochemical proxies indicated that AR-F contains total organic matter and sulfur contents in the ranges of 0.89–3.32 and 0.30–2.73 wt %, respectively, confirming the marine environment for the studied samples. The presence of a marine environment, ranging from deep sea to slope and deep shelf, was also inferred by the large quantities of planktic forams and other marine skeletal assemblages, including bivalves and echinoderms, with rare ostracods. The Ni and V geochemical proxies, together with their ratios and enrichment factors, confirmed that these facies were mainly found in low oxygen environments, ranging from dysoxic to anoxic nonsulfidic conditions, thereby contributing to the preservation of organic matter. An Rb/Sr ratio of less than 0.1 indicated that the facies were accumulated in warm and humid climates, thereby resulting in an intensity of subaerial weathering. The dominant presence of warm-water plankton species (i.e., Globigerinoides sp.) together with a large number of primary producers (i.e., algae and dinocysts) in the Cenomanian–Turonian AR-F carbonate facies further suggested that warm climatic conditions occurred during OAE2. These warm climatic conditions can be the source of a mass influx of nutrients into the basins, which could be attributed to increased productivity of the water column. The high productivity was further supported by the presence of the shelf nannofossil taxon Zeugrhabdotus erectus. Such conditions resulted in high productivity and preservation of organic matter during OAE2, and thus, organic carbon-rich accumulation in the carbonate-rich sediments within the AR-F Member.

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埃及阿布-哈拉迪格油田阿布-罗阿什(F)富有机碳酸盐岩中的仙奥曼纪-震旦纪大洋缺氧事件 2 的特征及其对有机碳积累的影响
新特提斯洋(Neo-Tethys Ocean)南部的氧化还原条件期间,气候扰动与海洋有机碳的超常生成有关。埃及西北部沙漠中的 Abu Roash-F 碳酸盐就是在这一时期沉积的。这项研究揭示了一些有机和无机地球化学结果,并结合对埃及 Abu Gharadig 盆地两口勘探井中白垩纪中期 Abu Roash-F 成员碳酸盐岩的显微镜检查。这项工作的目的是了解仙人纪-震旦纪大洋缺氧事件 2(OAE2)期间的古环境条件及其对阿布鲁阿什(F)碳酸盐岩富含有机碳堆积的影响。地球化学代用指标表明,阿布鲁阿什碳酸盐岩的总有机质和硫含量分别为 0.89-3.32 和 0.30-2.73 wt %,证实了所研究样本所处的海洋环境。大量的浮游有孔虫和其他海洋骨骼组合,包括双壳类和棘皮动物,以及罕见的梭形纲动物,也推断出存在从深海到斜坡和深海陆架的海洋环境。镍和钒地球化学代用指标及其比率和富集因子证实,这些地层主要存在于低氧环境中,从缺氧到缺氧的非硫化条件不等,从而促进了有机质的保存。铷/锶比值小于 0.1 表明这些岩层是在温暖潮湿的气候条件下堆积的,因此造成了强烈的亚风化。暖水浮游生物物种(即 Globigerinoides sp.)以及大量初级生产者(即藻类和二叠体)在仙人漫纪-震旦纪 AR-F 碳酸盐岩层中的主要存在进一步表明,在 OAE2 期间出现了温暖的气候条件。这些温暖的气候条件可能是大量营养物质涌入盆地的源头,从而导致水体生产力的提高。陆架化石类群直立宙(Zeugrhabdotus erectus)的出现进一步支持了高生产力。这种条件导致了 OAE2 期间的高生产力和有机物的保存,从而使 AR-F 成员内富含碳酸盐的沉积物中积累了丰富的有机碳。
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来源期刊
ACS Earth and Space Chemistry
ACS Earth and Space Chemistry Earth and Planetary Sciences-Geochemistry and Petrology
CiteScore
5.30
自引率
11.80%
发文量
249
期刊介绍: The scope of ACS Earth and Space Chemistry includes the application of analytical, experimental and theoretical chemistry to investigate research questions relevant to the Earth and Space. The journal encompasses the highly interdisciplinary nature of research in this area, while emphasizing chemistry and chemical research tools as the unifying theme. The journal publishes broadly in the domains of high- and low-temperature geochemistry, atmospheric chemistry, marine chemistry, planetary chemistry, astrochemistry, and analytical geochemistry. ACS Earth and Space Chemistry publishes Articles, Letters, Reviews, and Features to provide flexible formats to readily communicate all aspects of research in these fields.
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