Development of biocomposites using cardanol oil bio-toughener, palm kernel fiber and chitosan derived from discarded biomass wastes: a characterization study with aging conditions

Abstract

This study focuses on the creation of high degree biocomposite with the utilization of renewable resources, including cardanol oil, palm kernel fiber and chitosan biopolymer. The principal aim of this research was to achieve high degree ratio of biocomposite for safe and eco-friendly application. The chitosan biopolymer was extracted from marine waste sea urchin spikes via deproteination. The biocomposites were prepared via hand layup technique following testing via ASTM standards. According to results, among the composites fabricated, PC5 exhibits exceptional mechanical strength with tensile strength of 88.2 MPa, flexural strength of 133.35 MPa and impact energy of 3.92 J. Therefore, PC6 composite performs better wear resistance with reduced coefficient of friction of 0.399 and Sp. wear rate of 0.01 mm³/Nm, respectively. And also, PC6 provides good thermal resistance with initial decomposition temperature of 345 °C. Similar to mechanical properties, in fatigue behavior also PC5 exhibits high fatigue life cycle counts with 19,647 for 25% UTS, 18,799 for 50% UTS and 17,571 for 75% UTS. The obtained results show that the inclusion of palm kernel fiber and chitosan significantly enhances the mechanical properties, wear and thermal resistance of the composites, while the cardinal oil binder ensures proper adhesion. However, thermal aging conditions were implemented to assess the material’s ability to withstand harsh environmental factors. Notably, among the composite materials tested, the designations with chitin (such as PC4, PC5, and PC6) exhibited lesser susceptibility to the effects of thermal aging. This resilience is attributed to the presence of NH₂ functional groups within chitin, which play a role in reducing the impact of thermal aging. These discoveries highlight the promising qualities of the developed polyester biocomposites, suggesting their suitability for a wide array of industrial applications requiring materials capable of enduring high-temperature environments such as automotive door panels, structural, space, defense and sports applications.