Synthesis, Structure, and Reactivity of Ruthenium-Indane Complexes with Diphosphine Ligand

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR European Journal of Inorganic Chemistry Pub Date : 2024-07-30 DOI:10.1002/ejic.202400415

Masumi Itazaki, Natsumi Kitani, Yukako Dobashi, Kento Okabayashi, Hiroshi Nakazawa, Toshiyuki Moriuchi

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Abstract

Ruthenium-indane complex, fac-[Ru(NCMe)₃(CO)₂(InCl₃)] 1Cl reacted with 0.5 equiv. of dppe/dppp to afford dinuclear ruthenium-indane complexes linked by diphosphine ligand, [{Ru(NCMe)₂(CO)₂(InCl₃)}₂{μ₂-Ph₂P(CH₂)_nPPh₂}] (n=2: 3, 3: 4). On the other hand, the reaction of fac-[Ru(NCMe)₃(CO)₂(InCl₃)] 1Cl with 1 equiv. of dppp afforded the corresponding chelate ruthenium(0) indane complex, [Ru(NCMe)(CO)₂(InCl₃)(dppp)] 5. In the case of dppm, a chelate complex [Ru(NCMe)(CO)₂(InCl₃)(dppm)] 6 was formed via the dinuclear Ru complex [{Ru(NCMe)₂(CO)₂(InCl₃)}₂(μ₂-dppm)]. Complexes 1Cl, 5, and 6 showed a catalytic activity for double-hydrosilylation of MeCN. Complexes 3–6 were fully characterized using NMR measurements, elemental analyses, and the structures of 1Cl, 3, 5, and 6 were determined by X-ray crystallography.

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含二膦配体的钌-茚配合物的合成、结构和反应活性

钌-茚配合物 fac-[Ru(NCMe)3(CO)2(InCl3)] 1Cl 与 0.5 等量的 dppe/dppp 反应，得到由二膦配体连接的双核钌-茚配合物 [Ru(NCMe)2(CO)2(InCl3)]2(η2,μ2-Ph2P(CH2)nPPh2)（n = 2：3，3：4）。另一方面，面-[Ru(NCMe)3(CO)2(InCl3)]与 1 等量的 dppp 反应得到相应的螯合钌（0）茚络合物 [Ru(NCMe)(CO)2(InCl3)(dppp)]5。在 dppm 的情况下，通过二核 Ru 复合物 [Ru(NCMe)2(CO)2(InCl3)]2(η2,μ2-Ph2PCH2PPh2)，形成了螯合物 [Ru(NCMe)(CO)2(InCl3)(dppm)] 6。络合物 1Cl、5 和 6 对乙腈的双氢硅烷化具有催化活性。利用核磁共振测量和元素分析对络合物 3-6 进行了全面表征，并通过 X 射线晶体学确定了 1Cl、3、5 和 6 的结构。

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.