Fretting-corrosion mechanisms of Ti6Al4V against CoCrMo in simulated body fluid under various fretting states

IF 6.3 1区 工程技术 Q1 ENGINEERING, MECHANICAL Friction Pub Date : 2024-08-05 DOI:10.1007/s40544-024-0909-0
Jian Pu, Zupei Zhang, Yali Zhang, Xiaogang Zhang, Xinlu Yuan, Xiaoyu Zhang, Guoxian Zhang, Wen Cui, Shu Yang, Zhongmin Jin
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Abstract

Ti6Al4V alloy–CoCrMo alloy pair is commonly applied for modular head–neck interfaces for artificial hip joint. Unfortunately, the fretting corrosion damage at this interface seriously restricts its lifespan. This work studied the fretting corrosion of Ti6Al4V–CoCrMo pair in calf serum solution. We established this material pair’s running condition fretting map (RCFM) regarding load and displacement, and revealed the damage mechanism of this material pair in various fretting regimes, namely partial slip regime (PSR), mixed fretting regime (MFR), and gross slip regime (GSR). The damage mechanism of Ti6Al4V alloy was mainly abrasive wear induced by CoCrMo alloy and tribocorrosion. Adhesive wear (material transfer) also existed in MFR. The damage mechanism of CoCrMo alloy was mainly abrasive wear induced by metal oxides and tribocorrosion in GSR and MFR, while no apparent damage in PSR. Furthermore, a dense composite material layer with high hardness was formed in the middle contacting area in GSR, which reduced the corrosion and wear of Ti alloys and exacerbated damage to Co alloys. Finally, the ion concentration maps for Ti and Co ions were constructed, which displayed the transition in the amount of released Ti and Co ions under different displacements and loads.

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不同摩擦状态下模拟体液中 Ti6Al4V 与 CoCrMo 的摩擦腐蚀机理
Ti6Al4V 合金-CoCrMo 合金对通常用于人工髋关节的模块化头颈接口。遗憾的是,该界面的烧蚀损坏严重限制了其使用寿命。本研究对 Ti6Al4V-CoCrMo 合金对在小牛血清溶液中的摩擦腐蚀进行了研究。我们建立了该材料对在载荷和位移方面的运行状态烧蚀图(RCFM),并揭示了该材料对在不同烧蚀状态下的损伤机理,即部分滑移状态(PSR)、混合烧蚀状态(MFR)和总滑移状态(GSR)。Ti6Al4V 合金的损伤机制主要是 CoCrMo 合金引起的磨料磨损和摩擦腐蚀。在 MFR 中也存在粘着磨损(材料转移)。在 GSR 和 MFR 中,CoCrMo 合金的损伤机制主要是金属氧化物引起的磨料磨损和摩擦腐蚀,而在 PSR 中没有明显的损伤。此外,在 GSR 中,中间接触区形成了高硬度的致密复合材料层,这降低了 Ti 合金的腐蚀和磨损,加剧了 Co 合金的损伤。最后,构建了钛和钴离子的离子浓度图,显示了在不同位移和载荷下钛和钴离子释放量的变化。
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来源期刊
Friction
Friction Engineering-Mechanical Engineering
CiteScore
12.90
自引率
13.20%
发文量
324
审稿时长
13 weeks
期刊介绍: Friction is a peer-reviewed international journal for the publication of theoretical and experimental research works related to the friction, lubrication and wear. Original, high quality research papers and review articles on all aspects of tribology are welcome, including, but are not limited to, a variety of topics, such as: Friction: Origin of friction, Friction theories, New phenomena of friction, Nano-friction, Ultra-low friction, Molecular friction, Ultra-high friction, Friction at high speed, Friction at high temperature or low temperature, Friction at solid/liquid interfaces, Bio-friction, Adhesion, etc. Lubrication: Superlubricity, Green lubricants, Nano-lubrication, Boundary lubrication, Thin film lubrication, Elastohydrodynamic lubrication, Mixed lubrication, New lubricants, New additives, Gas lubrication, Solid lubrication, etc. Wear: Wear materials, Wear mechanism, Wear models, Wear in severe conditions, Wear measurement, Wear monitoring, etc. Surface Engineering: Surface texturing, Molecular films, Surface coatings, Surface modification, Bionic surfaces, etc. Basic Sciences: Tribology system, Principles of tribology, Thermodynamics of tribo-systems, Micro-fluidics, Thermal stability of tribo-systems, etc. Friction is an open access journal. It is published quarterly by Tsinghua University Press and Springer, and sponsored by the State Key Laboratory of Tribology (TsinghuaUniversity) and the Tribology Institute of Chinese Mechanical Engineering Society.
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