Gayane S. Tonoyan , Gerald Giester , Vahram V. Ghazaryan , Ruben Yu. Chilingaryan , Arthur A. Margaryan , Artak H. Mkrtchyan , Aram M. Petrosyan
{"title":"Crystal structure of bis(β-alaninium) tetrabromidoplumbate","authors":"Gayane S. Tonoyan , Gerald Giester , Vahram V. Ghazaryan , Ruben Yu. Chilingaryan , Arthur A. Margaryan , Artak H. Mkrtchyan , Aram M. Petrosyan","doi":"10.1107/S2056989024007722","DOIUrl":null,"url":null,"abstract":"<div><p>This work focused on characterizing the structure from a stereochemical point of view, discussing the Pb<sup>II</sup> character. The XRD data were collected at 200 K.</p></div><div><p>The title compound, poly[bis(β-alaninium) [[dibromidoplumbate]-di-μ-dibromido]] {(C<sub>2</sub>H<sub>8</sub>NO<sub>2</sub>)<sub>2</sub>[PbBr<sub>4</sub>]}<sub>n</sub> or (<em>β</em>-AlaH)<sub>2</sub>PbBr<sub>4</sub>, crystallizes in the monoclinic space group <em>P</em>2<sub>1</sub>/<em>n</em>. The (PbBr<sub>4</sub>)<sup>2−</sup> anion is located on a general position and has a two-dimensional polymeric structure. The Pb center is holodirected. The supramolecular network is mainly based on O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds.</p></div>","PeriodicalId":7367,"journal":{"name":"Acta Crystallographica Section E: Crystallographic Communications","volume":"80 9","pages":"Pages 931-935"},"PeriodicalIF":0.5000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section E: Crystallographic Communications","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2056989024001841","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
Abstract
This work focused on characterizing the structure from a stereochemical point of view, discussing the PbII character. The XRD data were collected at 200 K.
The title compound, poly[bis(β-alaninium) [[dibromidoplumbate]-di-μ-dibromido]] {(C2H8NO2)2[PbBr4]}n or (β-AlaH)2PbBr4, crystallizes in the monoclinic space group P21/n. The (PbBr4)2− anion is located on a general position and has a two-dimensional polymeric structure. The Pb center is holodirected. The supramolecular network is mainly based on O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds.
期刊介绍:
Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.