Sajal Kar, Sheelbhadra Chatterjee, S. Bandyopadhyay
{"title":"A multi-stimuli responsive spiropyran-tetraphenylethene conjugate for the control of near-infrared emission","authors":"Sajal Kar, Sheelbhadra Chatterjee, S. Bandyopadhyay","doi":"10.1055/a-2383-0905","DOIUrl":null,"url":null,"abstract":"The synthesis of a dinitrotetraphenylethene linked to two photochromic spiropyran moeities was achieved. The compound displays photochromic and acidochrmic behavior. In the aggregated merocyanine photoisomeric state, the molecule is prone to form aggregates of the zwitterionic form. The merocyanine form displays near-infrared intense fluorescence (λmax_em. at 665 nm) extending into the near-infrared region up to 900 nm. On the other hand, the spiropyran form displays fluorescence in the 450 nm region. In DMF water-mixture, the near-infrared emission is quenched whereas the spiropyran form displays fluorescence with a λmax_em. at 563 nm.","PeriodicalId":501298,"journal":{"name":"Synthesis","volume":"100 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1055/a-2383-0905","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The synthesis of a dinitrotetraphenylethene linked to two photochromic spiropyran moeities was achieved. The compound displays photochromic and acidochrmic behavior. In the aggregated merocyanine photoisomeric state, the molecule is prone to form aggregates of the zwitterionic form. The merocyanine form displays near-infrared intense fluorescence (λmax_em. at 665 nm) extending into the near-infrared region up to 900 nm. On the other hand, the spiropyran form displays fluorescence in the 450 nm region. In DMF water-mixture, the near-infrared emission is quenched whereas the spiropyran form displays fluorescence with a λmax_em. at 563 nm.
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