A High-Temperature Thermocouple Development by Additive Manufacturing: Tungsten-Nickel (W-Ni) and Molybdenum (Mo) Integration with Ceramic Structures

Azizul Islam, Vamsi Borra, Pedro Cortes
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Abstract

Additive manufacturing holds more potential to enable the development of ceramic-based components. Ceramics offer high resistance to heat, high fracture toughness, and are extremely corrosion resistant. Thus, ceramics are widely used in sectors such as the aerospace industry, automotive, microelectronics, and biomedicine. Using various additive manufacturing platforms, ceramics with complex and uniquely designed geometry can be developed to suit specific applications. This project aims at innovating high-temperature thermocouples by embedding conductive metal pastes into a ceramic structure. The paste used includes tungsten, molybdenum, and antimony. The metal pastes are precisely extruded into a T-shaped trench inside the ceramic matrix. Following specific temperature ranges, the ceramic matrix is sintered to improve the properties of the material. The sensors produced can function at extremely high temperatures and are thereby suitable for high-temperature environments. Comparative testing of the 3D sintered sensors with conventional temperature sensors shows high correlation between the two classes of sensors. The resulting R-squared value of 0.9885 is satisfactory which implies the reliability and accuracy of 3D sintering sensors are satisfactory in temperature sensing applications.
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利用增材制造技术开发高温热电偶:钨镍(W-Ni)和钼(Mo)与陶瓷结构的整合
快速成型技术在开发陶瓷组件方面具有更大的潜力。陶瓷具有高耐热性、高断裂韧性和极强的耐腐蚀性。因此,陶瓷被广泛应用于航空航天、汽车、微电子和生物医学等领域。利用各种快速成型制造平台,可以开发出具有复杂和独特设计几何形状的陶瓷,以满足特定应用的需要。本项目旨在通过在陶瓷结构中嵌入导电金属浆料来创新高温热电偶。使用的浆料包括钨、钼和锑。金属浆料被精确地挤入陶瓷基体内部的 T 形沟槽中。在特定的温度范围内,陶瓷基体被烧结,以提高材料的性能。生产出的传感器可在极高温度下工作,因此适用于高温环境。三维烧结传感器与传统温度传感器的对比测试表明,两类传感器之间具有很高的相关性。由此得出的 R 平方值为 0.9885,令人满意,这意味着三维烧结传感器在温度传感应用中的可靠性和准确性令人满意。
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