Using in situ measurements of δ13C in methane to investigate methane emissions from the western Canada sedimentary basin

IF 3.8 Q2 ENVIRONMENTAL SCIENCES Atmospheric Environment: X Pub Date : 2024-08-01 DOI:10.1016/j.aeaoa.2024.100286
Sébastien Ars , Gabriela González Arismendi , Karlis Muehlenbachs , Douglas E.J. Worthy , Felix Vogel
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Abstract

During COP26, Canada joined the Global Methane Pledge aiming to reduce global methane (CH4) emissions by 30% below 2020 levels by 2030. Rapid reduction of anthropogenic CH4 emissions in the atmosphere is considered one of the most effective strategies to slow global warming in concert with carbon dioxide mitigation measures. In Canada, a large part of anthropogenic CH4 emissions can be attributed to the oil and gas industry in the Western Canada Sedimentary Basin (WCSB), which is the fourth largest reserve of fossil fuel in the world. Recent studies highlighted big discrepancies between CH4 emissions reported in Canada's National Inventory and emissions estimated with approaches using atmospheric measurements for the oil and gas sector. Measuring the isotopic signature of CH413CH4) at different atmospheric monitoring stations and comparing these measurements to detailed archives of δ13CH4 from oil and gas wells and associated CH4 leaks in the WCSB could help better characterize the emissions from different CH4 sources over the region. In this study, we compare two independent sets of data: (1) thousands of δ13CH4 of samples from oil and gas production wells and their associated leaks (surface casing vents and ground migration) collected across the WCSB, and (2) atmospheric mixing ratios of CH4 and their δ13CH4 measured successively at three locations across this region between 2016 and 2020 combined with their atmospheric footprints modeled with HYSPLIT-STILT. We observed a gradient in the isotopic signatures of the oil and gas samples within the WCSB with δ13CH4 being more depleted in the Southeast than in the Northwest. The analysis of these samples showed that the isotopic signature of CH4 emitted by the production of fossil fuel depends on the geological formations from which it is extracted. Also, CH4 isotopic signatures vary more depending on the region where CH4 comes from than on the type of fossil fuel extracted (natural gas, oil, heavy oil, shale gas). The atmospheric measurements showed a strong seasonality of δ13CH4 at one of the atmospheric monitoring sites with isotopic signatures associated with thermogenic sources in winter and isotopic signatures associated with a mix of biogenic and thermogenic sources in summer. Using the δ13CH4 archive database from oil and gas samples, we estimated that 28–39 % of the CH4 emitted near this site in summer was coming from a biogenic source (most likely wetlands). Ultimately, atmospheric measurements collected during winter combined with their associated HYSPLIT-STILT footprints presented a spatial distribution of δ13CH4 over the WCSB comparable to the one observed in the archive database from the oil and gas sector, confirming that the oil and gas sector is the main source of CH4 in this region.

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利用甲烷中的δ13C 原位测量数据调查加拿大西部沉积盆地的甲烷排放情况
在 COP26 期间,加拿大加入了全球甲烷承诺,旨在到 2030 年将全球甲烷(CH4)排放量从 2020 年的水平减少 30%。迅速减少大气中人为甲烷(CH4)排放量被认为是与二氧化碳减排措施共同减缓全球变暖的最有效战略之一。在加拿大,很大一部分人为甲烷排放可归因于加拿大西部沉积盆地(WCSB)的石油和天然气工业,该盆地是世界第四大化石燃料储藏地。最近的研究突出表明,加拿大国家清单中报告的甲烷排放量与使用大气测量方法估算的石油和天然气行业排放量之间存在巨大差异。在不同的大气监测站测量 CH4 的同位素特征(δ13CH4),并将这些测量结果与来自西部和南部非洲的油气井及相关 CH4 泄漏的详细δ13CH4 档案进行比较,有助于更好地确定该地区不同 CH4 排放源的排放特征。在本研究中,我们比较了两组独立的数据:(1)在整个世界南极海盆区收集的数千个油气生产井及其相关泄漏(地面套管喷口和地面迁移)样本的δ13CH4;(2)2016 年至 2020 年期间在该地区三个地点连续测量的 CH4 大气混合比及其δ13CH4,并结合使用 HYSPLIT-STILT 模拟的大气足迹。我们观察到,西西伯利亚盆地内油气样本的同位素特征存在梯度,东南部的 δ13CH4 比西北部更贫化。对这些样本的分析表明,化石燃料生产过程中排放的 CH4 的同位素特征取决于其开采的地质构造。此外,CH4 同位素特征的变化更多地取决于 CH4 的来源地区,而不是开采的化石燃料类型(天然气、石油、重油、页岩气)。大气测量结果显示,其中一个大气监测点的 δ13CH4 具有很强的季节性,冬季的同位素特征与热源有关,而夏季的同位素特征则与生物源和热源混合有关。利用石油和天然气样本的 δ13CH4 档案数据库,我们估计该站点附近夏季排放的 CH4 中有 28%-39% 来自生物源(很可能是湿地)。最终,冬季收集的大气测量数据与相关的 HYSPLIT-STILT 脚印相结合,显示出世界南极海盆区的δ13CH4 空间分布与石油和天然气行业档案数据库中观察到的分布相当,从而证实石油和天然气行业是该地区 CH4 的主要来源。
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来源期刊
Atmospheric Environment: X
Atmospheric Environment: X Environmental Science-Environmental Science (all)
CiteScore
8.00
自引率
0.00%
发文量
47
审稿时长
12 weeks
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