Catalytic reactions promoted by metal complexes stabilized by 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. A brief survey of recent results
{"title":"Catalytic reactions promoted by metal complexes stabilized by 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. A brief survey of recent results","authors":"","doi":"10.1016/j.ica.2024.122295","DOIUrl":null,"url":null,"abstract":"<div><p>In this review article, we present a brief survey of the recent contributions (2018–2024) appeared in the scientific literature, describing the use of the cage-like water-soluble monodentate phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (also known as 1,3,5-triaza-7-phosphadamantane, PTA), some of its derivatives and a higher homologue as stabilizing ligands for precious and non-precious metal complexes, with various applications in homogeneous catalytic processes in water and biphasic media.</p></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0020169324003864/pdfft?md5=9606090ff8d8449a886c73ec0c1640ec&pid=1-s2.0-S0020169324003864-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0020169324003864","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
In this review article, we present a brief survey of the recent contributions (2018–2024) appeared in the scientific literature, describing the use of the cage-like water-soluble monodentate phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (also known as 1,3,5-triaza-7-phosphadamantane, PTA), some of its derivatives and a higher homologue as stabilizing ligands for precious and non-precious metal complexes, with various applications in homogeneous catalytic processes in water and biphasic media.
期刊介绍:
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.