Photocatalytic applications and synthetic strategies of Ti and Fe-based MOFs

IF 2.7 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Inorganica Chimica Acta Pub Date : 2024-08-13 DOI:10.1016/j.ica.2024.122297

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Abstract

Metal-organic frameworks (MOFs) have emerged as promising materials for photocatalytic applications due to their tunable structures and exceptional surface areas. Among various types of MOFs, those based on titanium (Ti) and iron (Fe) have garnered significant attention for their potential in environmental remediation, energy conversion, and organic synthesis. This review paper comprehensively examines the recent advancements in the photocatalytic applications and synthetic strategies of Ti and Fe-based MOFs. In the first part, we provide an in-depth analysis of the synthetic strategies employed for the preparation of Ti and Fe-based MOFs with tailored photocatalytic properties. The second part of the review highlights the diverse photocatalytic applications of Ti and Fe-based MOFs, including environmental remediation through the degradation of organic pollutants, hydrogen evolution reaction (HER) for renewable energy production, carbon dioxide reduction for greenhouse gas mitigation, and catalysis of organic transformations. Overall, this review paper offers valuable insights into the current state-of-the-art in the field of Ti and Fe-based MOFs for photocatalytic applications, providing researchers and practitioners with a comprehensive understanding of the potential and limitations of these materials. The synthesis strategies discussed herein serve as guidelines for the rational design and development of highly efficient photocatalysts for various environmental and energy-related applications.

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钛基和铁基 MOF 的光催化应用和合成策略

金属有机框架（MOFs）因其可调整的结构和特殊的比表面积，已成为光催化应用中极具前景的材料。在各种类型的 MOFs 中，基于钛（Ti）和铁（Fe）的 MOFs 因其在环境修复、能源转换和有机合成方面的潜力而备受关注。本综述全面探讨了钛基和铁基 MOFs 在光催化应用和合成策略方面的最新进展。在第一部分中，我们深入分析了制备具有定制光催化特性的钛基和铁基 MOFs 所采用的合成策略。综述的第二部分重点介绍了钛基和铁基 MOFs 的各种光催化应用，包括通过降解有机污染物进行环境修复、用于可再生能源生产的氢进化反应 (HER)、用于减缓温室气体排放的二氧化碳减排以及有机转化催化。总之，这篇综述论文为了解当前钛基和铁基 MOFs 在光催化应用领域的最新进展提供了宝贵的见解，使研究人员和从业人员对这些材料的潜力和局限性有了全面的了解。本文讨论的合成策略可作为合理设计和开发用于各种环境和能源相关应用的高效光催化剂的指南。

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来源期刊

Inorganica Chimica Acta 化学-无机化学与核化学

CiteScore

6.00

自引率

3.60%

发文量

440

审稿时长

35 days

期刊介绍： Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews. Topics covered include: • chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies; • synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs); • reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models; • applications of inorganic compounds, metallodrugs and molecule-based materials. Papers composed primarily of structural reports will typically not be considered for publication.