Preparation and properties of an anti-icing and de-icing emulsified asphalt coating containing RTV and CNTs

IF 6.5 2区 材料科学 Q1 CHEMISTRY, APPLIED Progress in Organic Coatings Pub Date : 2024-08-12 DOI:10.1016/j.porgcoat.2024.108736
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Abstract

In regions experiencing cold weather, road icing poses significant challenges to transportation safety. Traditional anti-icing or de-icing methods, such as salt spraying, have raised environmental concerns, prompting the exploration of more sustainable alternatives. This study introduces a novel approach by developing a hydrophobic coating for road surfaces. This method involves using room-temperature vulcanized silicone rubber (RTV) and carbon nanotubes (CNTs) for the hydrophobic modification of emulsified asphalt (EA), resulting in the preparation of modified emulsified asphalt (RCEA). This method does not cause environmental pollution and makes the road surface highly hydrophobic and effective at preventing ice formation. When the dosages of RTV and CNTs are 20 wt% and 4 wt%, respectively, the contact angle of RCEA reaches 118.6°, showing a significant increase of 73.4 % compared to EA. Comparative tests have revealed that RCEA extends the freezing time of water droplets by 66.7 % at −10 °C compared to traditional emulsified asphalt (EA). Furthermore, the adhesion force of ice on the RCEA surface is 58.2 % lower than on EA, indicating significantly improved de-icing efficiency. The results of ultraviolet aging and freeze-thaw cycle tests show that RCEA maintains its hydrophobicity, evidenced by only a slight reduction in the contact angle. Additionally, water seepage coefficient tests and anti-skid performance assessments confirm that RCEA meets the requisite standards for road performance. In summary, RCEA emerges as a promising anti-icing and de-icing material for asphalt roads, offering an environmentally friendly alternative to traditional de-icing methods.

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含 RTV 和 CNT 的防冰和除冰乳化沥青涂层的制备及其性能
在天气寒冷的地区,道路结冰给交通安全带来了巨大挑战。传统的防冰或除冰方法(如盐喷洒)引起了环境问题,促使人们探索更可持续的替代方法。本研究通过开发路面疏水涂层引入了一种新方法。该方法包括使用室温硫化硅橡胶(RTV)和碳纳米管(CNTs)对乳化沥青(EA)进行疏水改性,从而制备出改性乳化沥青(RCEA)。这种方法不会造成环境污染,而且能使路面具有很强的疏水性,有效防止结冰。当 RTV 和 CNT 的用量分别为 20 wt% 和 4 wt% 时,RCEA 的接触角达到 118.6°,与 EA 相比显著增加了 73.4%。对比测试表明,与传统的乳化沥青(EA)相比,RCEA 可将水滴在零下 10 °C 的凝结时间延长 66.7%。此外,冰在 RCEA 表面的附着力比在 EA 表面低 58.2%,这表明除冰效率显著提高。紫外线老化和冻融循环测试结果表明,RCEA 保持了其疏水性,接触角仅略有减小。此外,渗水系数测试和防滑性能评估证实,RCEA 符合道路性能的必要标准。总之,RCEA 是一种很有前途的沥青路面防冰和除冰材料,是传统除冰方法的环保型替代品。
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来源期刊
Progress in Organic Coatings
Progress in Organic Coatings 工程技术-材料科学:膜
CiteScore
11.40
自引率
15.20%
发文量
577
审稿时长
48 days
期刊介绍: The aim of this international journal is to analyse and publicise the progress and current state of knowledge in the field of organic coatings and related materials. The Editors and the Editorial Board members will solicit both review and research papers from academic and industrial scientists who are actively engaged in research and development or, in the case of review papers, have extensive experience in the subject to be reviewed. Unsolicited manuscripts will be accepted if they meet the journal''s requirements. The journal publishes papers dealing with such subjects as: • Chemical, physical and technological properties of organic coatings and related materials • Problems and methods of preparation, manufacture and application of these materials • Performance, testing and analysis.
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